Answer:
The calorimeter constant is = 447 J/°C
Explanation:
The heat absorbed or released (Q) by water can be calculated with the following expression:
Q = c × m × ΔT
where,
c is the specific heat
m is the mass
ΔT is the change in temperature
The water that is initially in the calorimeter (w₁) absorbs heat while the water that is added (w₂) later releases heat. The calorimeter also absorbs heat.
The heat absorbed by the calorimeter (Q) can be calculated with the following expression:
Q = C × ΔT
where,
C is the calorimeter constant
The density of water is 1.00 g/mL so 50.0 mL = 50.0 g. The sum of the heat absorbed and the heat released is equal to zero (conservation of energy).
Qabs + Qrel = 0
Qabs = - Qrel
Qcal + Qw₁ = - Qw₂
Qcal = - (Qw₂ + Qw₁)
Ccal . ΔTcal = - (cw . mw₁ . ΔTw₁ + cw . mw₂ . ΔTw₂)
Ccal . (30.31°C - 22.6°C) = - [(4.184 J/g.°C) × 50.0 g × (30.31°C - 22.6°C) + (4.184 J/g.°C) × 50.0 g × (30.31°C - 54.5°C)]
Ccal = 447 J/°C
Answer:
1.) AgNO₃
2.) 0.563 moles AgBr
Explanation:
The limiting reagent is the reagent that is used up completely during a reaction. It can be identified by calculating which reactant produces the smallest amount of product. This can be done by determining the number of moles of each reagent (via molarity conversion). and then converting it to moles of the product (via mole-to-mole ratio).
AgNO₃ (aq) + KBr (aq) ---> AgBr (s) + KNO₃ (aq)
Molarity (M) = moles / liters
100 mL = 1 L
AgNO₃
45.0 mL / 100 = 45.0 L
1.25 M = ? moles / 0.450 L
? moles = 0.563 moles
KBr
75.0 mL / 100 = 0.750 L
0.800 M = ? moles / 0.750 L
? moles = 0.600 moles
In this case, there is no need to use the mole-to-mole ratio because all of the coefficients are one in the reaction (the amount of the limiting reagent used is the same amount of product produced). Since AgNO₃ produces the smaller amount of product, it is the limiting reagent.
Answer:
Explanation:
In CF4 and NF3, the valence electron groups on the central C and N atoms have a tetrahedral arrangement. The shapes of the molecules are determined by the number of bonding and nonbonding of electrons: since CF4 has four bonded atom(s) and zero lone pair(s) of electrons, the shape is tetrahedral.
When light travels from air into water,it slows down,causing it to change directions slightly