Question

which conditions can result in deviations from beer's law when the pathlength is constant? all radiation not absorbed by the sample is transmitted to the detector the absorbing species undergoes dissociation or association the sample is homogeneous solute concentrations exceeding 0.01 m the use of polychromatic radiation

Answer 1

There are several conditions that can result in deviations from Beer's Law when the pathlength is constant. This can cause the Beer's Law plot to become non-linear.

When the solute concentrations exceed 0.01 m. This can cause the Beer's Law plot to become flat or even inverted. The use of polychromatic radiation can also cause deviations from Beer's Law. This is because different wavelengths of light will be absorbed to different degrees by the sample.

When the pathlength is constant, the conditions that can result in deviations from Beer's law are:

1) All radiation not absorbed by the sample is transmitted to the detector.

2) The absorbing species undergoes dissociation or association.

3) The sample is homogeneous.

4) Solute concentrations exceeding 0.01 M.

5) The use of polychromatic radiation.

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