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ddd [48]
1 year ago
13

Consider the molecule BF3. (a) What is the electron config- uration of an isolated B atom? (b) What is the electron con- figurat

ion of an isolated F atom? (c) What hybrid orbitals should be constructed on the B atom to make the B–F bonds in BF3? (d) What valence orbitals, if any, remain unhybrid- ized on the B atom in BF3?
Chemistry
1 answer:
anzhelika [568]1 year ago
8 0

For the given molecule, we are asked to give-

  1. The electron configuration of an isolated B atom
  2. The electron configuration of an isolated F atom
  3. Hybrid orbitals should be constructed on the B atom to make the B–F bonds in Boron tri flouride
  4. valence orbitals, if any, remain unhybridized on the B atom.
  • The electron configuration of an isolated B atom:

as atomic number of B is 5

electronic configuration will be [He] 2s² 2p¹

  • The electron configuration of an isolated F atom:

as atomic number of F is 9

electronic configuration will be  [He] 2s² 2p5

  • Hybrid orbitals should be constructed on the B atom to make the B–F bonds in Boron tri flouride will be sp2.

as the one s and two of p orbital from the valance shell will hybridised to make 3 hybrid orbital of B resulting in 3 B-F bonds.

  • valence orbitals, if any, remain unhybridized on the B atom will be 1

To know more about hybrisisation:

brainly.com/question/23038117

#SPJ4

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Answer:

a) ΔHvap=35.3395 kJ/mol

b) Tb=98.62 °C

Explanation:

Given the reaction:

C₇H₁₆ (l) ⇔ C₇H₁₆ (g)

Kp=P(C₇H₁₆) since the concentration ratio for a pure liquid is equal to 1.

When

T₁=50°C=323.15K ⇒P₁=0.179

T₂=86°C=359.15K ⇒P₂=0.669

The Clasius-Clapeyron equation is:

ln(\frac{P_2}{P_1}) =-\frac{AH_{vap}}{R} (\frac{1}{T_2}-\frac{1}{T_1})

ln(\frac{0.669}{0.179}) =-\frac{AH_{vap}}{8.3145 J.mol^{-1}K^{-1}} (\frac{1}{359.15K}-\frac{1}{323.15K})

1.3184 =-\frac{AH_{vap}}{8.3145 J.mol^{-1}K^{-1}} (-3.10186*10^{-4}K{^-1})

ΔHvap=35339.5 J/mol=35.3395 KJ/mol

Normal boiling point ⇒ P=1 atm

Hence, we find the normal boiling point where:

T₁=323.15K

P₁=0.179 atm

P₂=1 atm

ln(\frac{P_2}{P_1}) =-\frac{AH_{vap}}{R} (\frac{1}{T_2}-\frac{1}{T_1})

ln(\frac{1atm}{0.179atm}) =-\frac{35339.5 J/mol}{8.3145 J.mol^{-1}K^{-1}} (\frac{1}{T_2}-\frac{1}{323.15K})

1.7203=-4250.34 (\frac{1}{T_2}-\frac{1}{323.15K})

T₂=371.77 K= 98.62 °C

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3 years ago
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4 years ago
A 200.0 mL solution of 0.40 M ammonium chloride was titrated with 0.80 M sodium hydroxide. What was the pH of the solution after
choli [55]

Answer:

9.25

Explanation:

Let first find the moles of NH_4Cl and NaOH

number of moles of NH_4Cl = 0.40  mol/L × 200 ×  10⁻³L

= 0.08 mole

number of moles of NaOH = 0.80  mol/L × 50 ×  10⁻³L

= 0.04 mole

The equation for the reaction is expressed as:

NH^+_{4(aq)} \ + OH^-_{(aq)} ------> NH_{3(g)} \ + H_2O_{(l)}

The ICE Table is shown below as follows:

                            NH^+_{4(aq)} \ + OH^-_{(aq)} ------> NH_{3(g)} \ + H_2O_{(l)}

Initial (M)              0.08            0.04                            0

Change (M)         - 0.04          -0.04                          + 0.04

Equilibrium (M)      0.04             0                                0.04

K_a*K_b = 10^{-14} \ at \ 25^0C

K_a = \frac{10^{-14}}{K_b}

K_a = \frac{10^{-14}}{1.76*10^{-5}}

K_a= 5.68*10^{10}

pK_a = - log \ (K_a)

pK_a = - log \ (5.68*10^{-10})

pK_a = 9.25

pH = pKa + \ log (\frac{HB}{HA} )   for buffer solutions

pH = pKa + \ log (\frac{moles \ of \ base }{ moles\ of \ acid} ) since they are in the same solution

pH = 9.25 + \ log (\frac{0.04 }{ 0.04} )

pH = 9.25

8 0
3 years ago
Nuclear Chemistry Writing Assignment
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Answer:

21 years

% of parent isotope remaining before safe

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3 years ago
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How many grams of P4O10 would be produced when 0.700 mole of phosphorus is burned?
AysviL [449]
We can solve the equation and show the solution below:

Oxygen atomic number is 16.
Phosphorus atomic number is 32.

We have the molecular weight:
Molecular weight = (31*4) + (16*10)
Molecular weight = 284 grams/mol

Solving for the grams:

0.4 mole (for P4) * (1 mol P4O10/1 mol P4) * (284 grams P4O10/1 mole P4O10)
Total grams = 113.6

The answer is 113.6 grams.
8 0
3 years ago
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