the compound with the smaller lattice energy is potassium sulphide here the size of the molecule play a important role
The quantity of energy released by the electrostatic attraction of oppositely charged ions is known as lattice energy (L.E). The ion's size and charge affect the lattice energy.
lattice energy is inversely proportional to size of ion and directly proportional to charge of the ion. They are each charged equally that is plus two and minus two However, because the Sulphur is larger in size and the oxygen is lesser in this case, The lattice energy of potassium oxide is larger the lattice energy of potassium sulphide is smaller.
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Henderson–Hasselbalch equation is given as,
pH = pKa + log [A⁻] / [HA]
-------- (1)
Solution:
Convert Ka into pKa,
pKa = -log Ka
pKa = -log 1.37 × 10⁻⁴
pKa = 3.863
Putting value of pKa and pH in eq.1,
4.29 = 3.863 + log [lactate] / [lactic acid]
Or,
log [lactate] / [lactic acid] = 4.29 - 3.863
log [lactate] / [lactic acid] = 0.427
Taking Anti log,
[lactate] / [lactic acid]
= 2.673
Result:
2.673 M
lactate salt when mixed with 1 M Lactic acid produces a buffer of pH = 4.29.
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Explanation:
B. HCIO these is the answer
Answer : The heat of the reaction is -221.6 kJ
Explanation :
Heat released by the reaction = Heat absorbed by the calorimeter
where,
= heat released by the reaction = ?
= heat absorbed by the calorimeter
= specific heat of calorimeter = 
= change in temperature = 
Now put all the given values in the above formula, we get:
As,
So, 
Thus, the heat of the reaction is -221.6 kJ
