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IRINA_888 [86]
3 years ago
13

Write an equation to show how HC2O4− can act as a base with HS− acting as an acid.

Chemistry
1 answer:
Artyom0805 [142]3 years ago
7 0

An acid donates H^{+} ion in aqueous solution. A base accepts H^{+} ion in aqueous solution.

The equation representing the acid base reaction of HC_{2}O_{4}^{-} and HS^{-}:

HC_{2}O_{4}^{-}(aq) + HS^{-}(aq) ----> H_{2}C_{2}O_{4}(aq)+S^{2-}(aq)

In the above reaction, as HC_{2}O_{4}^{-} acts as a base it is accepting the hydrogen ion from HS^{-}. Similarly, HS^{-} donates its hydrogen ion to HC_{2}O_{4}^{-} acting as an acid.

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3. 2.15 x 3.1 x 100 =
jeka94

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666.5

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Will a precipitate of magnesium fluoride form when 300. mL of 1.1 × 10 –3 M MgCl 2 are added to 500. mL of 1.2 × 10 –3 M NaF? [K
Tju [1.3M]

Answer:

No precipitate is formed.

Explanation:

Hello,

In this case, given the dissociation reaction of magnesium fluoride:

MgF_2(s)\rightleftharpoons Mg^{2+}+2F^-

And the undergoing chemical reaction:

MgCl_2+2NaF\rightarrow MgF_2+2NaCl

We need to compute the yielded moles of magnesium fluoride, but first we need to identify the limiting reactant for which we compute the available moles of magnesium chloride:

n_{MgCl_2}=0.3L*1.1x10^{-3}mol/L=3.3x10^{-4}molMgCl_2

Next, the moles of magnesium chloride consumed by the sodium fluoride:

n_{MgCl_2}^{consumed}=0.5L*1.2x10^{-3}molNaF/L*\frac{1molCaCl_2}{2molNaF} =3x10^{-4}molMgCl_2

Thus, less moles are consumed by the NaF, for which the moles of formed magnesium fluoride are:

n_{MgF_2}=3x10^{-4}molMgCl_2*\frac{1molMgF_2}{1molMgCl_2}=3x10^{-4}molMgF_2

Next, since the magnesium fluoride to magnesium and fluoride ions is in a 1:1 and 1:2 molar ratio, the concentrations of such ions are:

[Mg^{2+}]=\frac{3x10^{-4}molMg^{+2}}{(0.3+0.5)L} =3.75x10^{-4}M

[F^-]=\frac{2*3x10^{-4}molMg^{+2}}{(0.3+0.5)L} =7.5x10^{-4}M

Thereby, the reaction quotient is:

Q=(3.75x10^{-4})(7.5x10^{-4})^2=2.11x10^{-10}

In such a way, since Q<Ksp we say that the ions tend to be formed, so no precipitate is formed.

Regards.

6 0
2 years ago
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