Answer:
The correct answer is "a quote from Mein Kampf written by Adolf Hitler".
Explanation:
Mein Kampf is a 1925 famous book written by Adolf Hitler that serves as an autobiographical manifesto of the Nazi Party that he led. The statement that is included in this paragraph belongs to a quote of this book. In this statement it is reflected the ideology of Adolf Hitler, denying democracy as a government and expressing its ideology of a totalitarian autocracy.
Equilibrium expression is ![Keq = \frac{[H3O+][HCO3^-]}{[H2CO3]}\\](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BH3O%2B%5D%5BHCO3%5E-%5D%7D%7B%5BH2CO3%5D%7D%5C%5C)
<u>Explanation:</u>
Equilibrium expression is denoted by Keq.
Keq is the equilibrium constant that is defined as the ratio of concentration of products to the concentration of reactants each raised to the power its stoichiometric coefficients.
Example -
aA + bB = cC + dD
So, Keq = conc of product/ conc of reactant
![Keq = \frac{[C]^c [D]^d}{[A]^a [B]^b}](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BC%5D%5Ec%20%5BD%5D%5Ed%7D%7B%5BA%5D%5Ea%20%5BB%5D%5Eb%7D)
So from the equation, H₂CO₃+H₂O = H₃O+HCO₃⁻¹
![Keq = \frac{[H3O^+]^1 [HCO3^-]^1}{[H2CO3]^1 [H2O]^1}](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BH3O%5E%2B%5D%5E1%20%5BHCO3%5E-%5D%5E1%7D%7B%5BH2CO3%5D%5E1%20%5BH2O%5D%5E1%7D)
The concentration of pure solid and liquid is considered as 1. Therefore, concentration of H2O is 1.
Thus,
![Keq = \frac{[H3O+][HCO3^-]}{[H2CO3]}\\](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BH3O%2B%5D%5BHCO3%5E-%5D%7D%7B%5BH2CO3%5D%7D%5C%5C)
Therefore, Equilibrium expression is ![Keq = \frac{[H3O+][HCO3^-]}{[H2CO3]}\\](https://tex.z-dn.net/?f=Keq%20%3D%20%5Cfrac%7B%5BH3O%2B%5D%5BHCO3%5E-%5D%7D%7B%5BH2CO3%5D%7D%5C%5C)
And what are the compounds?
C-c-c-c-c
|
c
c-c-c-c-c
|
c
c
|
c-c-c-c
|
c
c-c-c-c
| |
c c
Answer:
The boiling point is 308.27 K (35.27°C)
Explanation:
The chemical reaction for the boiling of titanium tetrachloride is shown below:
Ti
⇒ Ti
ΔH°
(Ti
) = -804.2 kJ/mol
ΔH°
(Ti
) = -763.2 kJ/mol
Therefore,
ΔH°
= ΔH°
(Ti
) - ΔH°
(Ti
) = -763.2 - (-804.2) = 41 kJ/mol = 41000 J/mol
Similarly,
s°(Ti
) = 221.9 J/(mol*K)
s°(Ti
) = 354.9 J/(mol*K)
Therefore,
s° = s° (Ti
) - s°(Ti
) = 354.9 - 221.9 = 133 J/(mol*K)
Thus, T = ΔH°
/s° = [41000 J/mol]/[133 J/(mol*K)] = 308. 27 K or 35.27°C
Therefore, the boiling point of titanium tetrachloride is 308.27 K or 35.27°C.