Answer:
ai) Rate law, ![Rate = k [CH_3 Cl] [Cl_2]^{0.5}](https://tex.z-dn.net/?f=Rate%20%3D%20k%20%5BCH_3%20Cl%5D%20%5BCl_2%5D%5E%7B0.5%7D)
aii) Rate constant, k = 1.25
b) Overall order of reaction = 1.5
Explanation:
Equation of Reaction:

If
, the rate of backward reaction is given by:
![Rate = k [A]^{a} [B]^{b}\\k = \frac{Rate}{ [A]^{a} [B]^{b}}\\k = \frac{Rate}{ [CH_3 Cl]^{a} [Cl_2]^{b}}](https://tex.z-dn.net/?f=Rate%20%3D%20k%20%5BA%5D%5E%7Ba%7D%20%5BB%5D%5E%7Bb%7D%5C%5Ck%20%3D%20%5Cfrac%7BRate%7D%7B%20%5BA%5D%5E%7Ba%7D%20%5BB%5D%5E%7Bb%7D%7D%5C%5Ck%20%3D%20%5Cfrac%7BRate%7D%7B%20%5BCH_3%20Cl%5D%5E%7Ba%7D%20%5BCl_2%5D%5E%7Bb%7D%7D)
k is constant for all the stages
Using the information provided in lines 1 and 2 of the table:
![0.014 / [0.05]^a [0.05]^b = 00.029/ [0.100]^a [0.05]^b\\0.014 / [0.05]^a [0.05]^b = 00.029/ [2*0.05]^a [0.05]^b\\0.014 / = 0.029/ 2^a\\2^a = 2.07\\a = 1](https://tex.z-dn.net/?f=0.014%20%2F%20%5B0.05%5D%5Ea%20%5B0.05%5D%5Eb%20%3D%2000.029%2F%20%5B0.100%5D%5Ea%20%5B0.05%5D%5Eb%5C%5C0.014%20%2F%20%5B0.05%5D%5Ea%20%5B0.05%5D%5Eb%20%3D%2000.029%2F%20%5B2%2A0.05%5D%5Ea%20%5B0.05%5D%5Eb%5C%5C0.014%20%2F%20%3D%200.029%2F%202%5Ea%5C%5C2%5Ea%20%3D%202.07%5C%5Ca%20%3D%201)
Using the information provided in lines 3 and 4 of the table and insering the value of a:
![0.041 / [0.100]^a [0.100]^b = 0.115 / [0.200]^a [0.200]^b\\0.041 / [0.100]^a [0.100]^b = 0.115 / [2 * 0.100]^a [2 * 0.100]^b\\](https://tex.z-dn.net/?f=0.041%20%2F%20%5B0.100%5D%5Ea%20%5B0.100%5D%5Eb%20%3D%200.115%20%2F%20%5B0.200%5D%5Ea%20%5B0.200%5D%5Eb%5C%5C0.041%20%2F%20%5B0.100%5D%5Ea%20%5B0.100%5D%5Eb%20%3D%200.115%20%2F%20%5B2%20%2A%200.100%5D%5Ea%20%5B2%20%2A%200.100%5D%5Eb%5C%5C)
![0.041 = 0.115 / [2 ]^a [2]^b\\ \[[2 ]^a [2]^b = 0.115/0.041\\ \[[2 ]^a [2]^b = 2.80\\\[[2 ]^1 [2]^b = 2.80\\\[[2]^b = 1.40\\b = \frac{ln 1.4}{ln 2} \\b = 0.5](https://tex.z-dn.net/?f=0.041%20%3D%200.115%20%2F%20%5B2%20%5D%5Ea%20%5B2%5D%5Eb%5C%5C%20%5C%5B%5B2%20%5D%5Ea%20%5B2%5D%5Eb%20%3D%200.115%2F0.041%5C%5C%20%5C%5B%5B2%20%5D%5Ea%20%5B2%5D%5Eb%20%3D%202.80%5C%5C%5C%5B%5B2%20%5D%5E1%20%5B2%5D%5Eb%20%3D%202.80%5C%5C%5C%5B%5B2%5D%5Eb%20%3D%201.40%5C%5Cb%20%3D%20%5Cfrac%7Bln%201.4%7D%7Bln%202%7D%20%5C%5Cb%20%3D%200.5)
The rate law is: ![Rate = k [CH_3 Cl] [Cl_2]^{0.5}](https://tex.z-dn.net/?f=Rate%20%3D%20k%20%5BCH_3%20Cl%5D%20%5BCl_2%5D%5E%7B0.5%7D)
The rate constant
then becomes:
![k = 0.014 / ( [0.050] [0.050]^(0.5) )\\k = 1.25](https://tex.z-dn.net/?f=k%20%3D%200.014%20%2F%20%28%20%5B0.050%5D%20%5B0.050%5D%5E%280.5%29%20%29%5C%5Ck%20%3D%201.25)
b) Overall order of reaction = a + b
Overall order of reaction = 1 + 0.5
Overall order of reaction = 1.5
Answer:
It could lead to Fatigue
Low energy.
Headaches.
Aches, pains, and tense muscles.
Chest pain and rapid heartbeat.
Explanation:
Protists belong to the group eukaryotes (having their DNA enclosed
inside the nucleus). They are not plants, nimals or fungi but they act like
one. They can be in general subgroups such as unicellular algae, protozoa and
molds. They thrive in environments with little sunlight. The answer is
letter B.