You would get 35.................
At the half equivalence point [HA] = [A-] and pH = pKa
<span>if Ka is 5.2e-5 then pKa = pH = 4.28</span>
The tea was no longer hot or (brewed) so the 5th didn’t dissolve like the others because the tea was hot or warm enough anymore it cooled down. So the sugar won’t dissolve no more.
Answer:
HOAc is stronger acid than HClO
ClO⁻ is stronger conjugate base than OAc⁻
Kb(OAc⁻) = 5.5 x 10⁻¹⁰
Kb(ClO⁻) = 3.3 x 10⁻⁷
Explanation:
Assume 0.10M HOAc => H⁺ + OAc⁻ with Ka = 1.8 x 10⁻⁵
=> [H⁺] = √Ka·[Acid] =√(1.8 x 10⁻⁵)(0.10) M = 1.3 x 10⁻³M H⁺
Assume 0.10M HClO => H⁺ + ClO⁻ with Ka = 3 x 10⁻⁸
=> [H⁺] = √(3 x 10⁻⁸)(0.10)M = 5.47 x 10⁻⁵M H⁺
HOAc delivers more H⁺ than HClO and is more acidic.
Kb = Kw/Ka, Kw = 1 x 10⁻¹⁴
Kb(OAc⁻) = 5.5 x 10⁻¹⁰
Kb(ClO⁻) = 3.3 x 10⁻⁷
