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vlabodo [156]
3 years ago
13

The constant k for a certain reaction is measured at two different temperatures:Temperature K376.0°C 4.8x 10^8280.0°C 2.3 x 10^8

Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy E for this reaction.
Chemistry
1 answer:
zaharov [31]3 years ago
3 0

Answer:

Explanation:

548888

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3 years ago
At 25 ∘C , the equilibrium partial pressures for the reaction were found to be PA=5.16 bar, PB=5.04 bar, PC=4.11 bar, and PD=4.8
erastova [34]

Answer: 5.85kJ/Kmol.

Explanation:

The balanced equilibrium reaction is

A(g)+2B(g)\rightleftharpoons 4C(g)+D(g)

The expression for equilibrium reaction will be,

K_p=\frac{[p_{D}]\times [p_{C}]}^4{[p_{B}]^2\times [p_{A}]}

Now put all the given values in this expression, we get the concentration of methane.

K_p=\frac{(4.85)\times [(4.11)^4}{(5.04)^2\times (5.16)}

K_p=10.6

Relation of standard change in Gibbs free energy and equilibrium constant is given by:

\Delta G^o=-2.303\times RT\times \log K_c

where,

R = universal gas constant = 8.314 J/K/mole

T = temperature = 25^0C=(25+273)K=298 K

K_c = equilibrium constant = 10.6

\Delta G^o=-2.303\times 8.314\times 298\times \log (10.6)

\Delta G^o=5850.23J/Kmol

\Delta G^o=5.85kJ/Kmol

Thus standard change in Gibbs free energy of this reaction is 5.85kJ/Kmol.

3 0
3 years ago
One gram of liquid benzene is burned in a bomb calorimeter. The temperature before ignition was 20.826 ℃, and the temperature af
gtnhenbr [62]

Answer:fH = - 3,255.7 kJ/mol

Explanation:Because the bomb calorimeter is adiabatic (q =0), there'is no heat inside or outside it, so the heat flow from the combustion plus the heat flow of the system (bomb, water, and the contents) must be 0.

Qsystem + Qcombustion = 0

Qsystem = heat capacity*ΔT

10000*(25.000 - 20.826) + Qc = 0

Qcombustion = - 41,740 J = - 41.74 kJ

So, the enthaply of formation of benzene (fH) at 298.15 K (25.000 ºC) is the heat of the combustion, divided by the number of moles of it. The molar mass od benzene is: 6x12 g/mol of C + 6x1 g/mol of H = 78 g/mol, and:

n = mass/molar mass = 1/ 78

n = 0.01282 mol

fH = -41.74/0.01282

fH = - 3,255.7 kJ/mol

4 0
3 years ago
Draw the structures of the following covalent molecules.
zysi [14]

NHCl_2=Attachment 1

SiO_2=Attachment 2

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BF_3=Attachment 4

CF_2H_2=Attachment 5

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2 years ago
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3 years ago
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