Use the chart to determine which pairs of atoms are arranged in the correct order according to increasing bond polarity?
2 answers:
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First we have to find Ka1 and Ka2
pKa1 = - log Ka1 so Ka1 = 0.059
pKa2 = - log Ka2 so Ka2 = 6.46 x 10⁻⁵
Looking at the values of equilibrium constants we can see that the first one is really big compared to second one. so, the pH will be affected mainly by the first ionization of the acid.
Oxalic acid is H₂C₂O₄
H₂C₂O₄ ⇄ H⁺ + HC₂O₄⁻
0.0356 M 0 0
0.0356 - x x x
Ka1 =![\frac{[H^+][HC2O4^-]}{[H2C2O4]}](https://tex.z-dn.net/?f=%20%5Cfrac%7B%5BH%5E%2B%5D%5BHC2O4%5E-%5D%7D%7B%5BH2C2O4%5D%7D%20)
= x² / 0.0356 - x
x = 0.025 M
pH = - log [H⁺] = - log (0.025) = 1.6
pKa1 = - log Ka1 so Ka1 = 0.059
pKa2 = - log Ka2 so Ka2 = 6.46 x 10⁻⁵
Looking at the values of equilibrium constants we can see that the first one is really big compared to second one. so, the pH will be affected mainly by the first ionization of the acid.
Oxalic acid is H₂C₂O₄
H₂C₂O₄ ⇄ H⁺ + HC₂O₄⁻
0.0356 M 0 0
0.0356 - x x x
Ka1 =
x = 0.025 M
pH = - log [H⁺] = - log (0.025) = 1.6
Answer:
(a) 0.779 mol Cr₂O₃
(b) 118 g Cr₂O₃
Explanation:
Step 1: Convert 156 g Cr₂S₃ to moles
Cr Molar Mass - 52.00 g/mol × 2 = 104.00 g/mol
S Molar Mass - 32.07 g/mol × 3 = 96.21 g/mol
156 g Cr₂S₃ ÷ 200.21 g/mol = 0.779182 mol Cr₂S₃
Step 2: Find conversion from Cr₂S₃ to Cr₂O₃
1 mol Cr₂S₃ equals 1 mol Cr₂O₃
Step 3: Use Dimensional Analysis
0.779182 mol Cr₂S₃ · = 0.779182 mol Cr₂O₃
0.779182 mol Cr₂O₃ ≈ 0.779 mol Cr₂O₃ (3 significant figures)
Step 4: Convert moles to grams
Cr Molar Mass - 52.00 g/mol × 2 = 104.00 g/mol
O Molar Mass - 16.00 g/mol × 3 = 48.00 g/mol
0.779182 mol Cr₂O₃ · 152.00 g/mol = 118.436 g Cr₂O₃
118.436 g Cr₂O₃ ≈ 118 g Cr₂O₃ (3 significant figures)