Answer:
Yes
2Ag + Cu(No3)2 -----(heat) ----- Cu + 2Agno3
When heat energy is passed through Cu(No3)2 then the reverse reaction will occur
Answer:
A i. Internal energy ΔU = -4.3 J ii. Internal energy ΔU = -6.0 J B. The second system is lower in energy.
Explanation:
A. We know that the internal energy,ΔU = q + w where q = quantity of heat and w = work done on system.
1. In the above q = -7.9 J (the negative indicating heat loss by the system). w = 3.6 J (It is positive because work is done on the system). So, the internal energy for this system is ΔU₁ = q + w = -7.9J + 3.6J = -4.3 J
ii. From the question q = +1.5 J (the positive indicating heat into the system). w = -7.5 J (It is negative because work is done by the system). So, the internal energy for this system is ΔU₂ = q + w = +1.5J + (-7.5J) = +1.5J - 7.5J = - 6.0J
B. We know that ΔU = U₂ - U₁ where U₁ and U₂ are the initial and final internal energies of the system. Since for the systems above, the initial internal energies U₁ are the same, then we say U₁ = U. Let U₁ and U₂ now represent the final energies of both systems in A i and A ii above. So, we write ΔU₁ = U₁ - U and ΔU₂ = U₂ - U where ΔU₁ and ΔU₂ are the internal energy changes in A i and A ii respectively. Now from ΔU₁ = U₁ - U, U₁ = ΔU₁ + U and U₂ = ΔU₂ + U. Subtracting both equations U₁ - U₂ = ΔU₁ - ΔU₂
= -4.3J -(-6.0 J)= 1.7 J. Since U₁ - U₂ > 0 , U₂ < U₁ , so the second system's internal energy increase less and is lower in energy and is more stable.
Answer:
The correct answer is option a.
Explanation:
Equilibrium concentration cadmium ions = ![[Cd^{2+}]=0.0585 M](https://tex.z-dn.net/?f=%5BCd%5E%7B2%2B%7D%5D%3D0.0585%20M)
Equilibrium concentration fluoride ions = ![[F^{-}]=0.117 M](https://tex.z-dn.net/?f=%5BF%5E%7B-%7D%5D%3D0.117%20M)
Molar solubility is the maximum concentration of salt present in water in ionic form beyond that no more salt will exist in its ionic form and will settle down in bottom of the solution.
The molar solubility of the solid cadmium fluoride = 0.0585 M
..[1]
Due to addition of sodium fluoride will increase concentration of fluoride in the solution.And due to common ion effect the equilibrium will shift in backward direction in [1], that is precipitation of more cadmium fluoride.
Hence, decrease in solubility will be observed.
