Answer:
Equation correctly showing the heat of solution

Explanation:
Mass of aqueous solution = m = 100 g
Specific heat of solution = c = 4.18 J/gºC
Change in temperature = 
ΔT = 21.6ºC - 30.0ºC = -8.4ºC
Heat lost by the solution = Q


Q = -3,511.2 J ≈ -3.51 kJ
Heat absorbed by potassium nitrate when solution in formed; Q'
Q' = -Q = 3.51 kJ
Moles of potassium nitrate , n= 

The heat of solution =

So, the equation correctly showing the heat of solution

Here's my best guess
the volume of the unit cell is (385*10^-12)^3=5.7066*10^-29 m^3
multiply by density to get mass
mass = (7 g/cm^3)*(100^3 cm^3 / 1^3 m^3) * 5.7066*10^-29 m^3= 3.99466*10^-22 g
covert to moles
3.99466*10^-22 g * 1 mol / 239.82 g = 1.6657 *10^-24 mol
convert to number of units
1.6657 *10^-24 mol * 6.23*10^23 units/mol = 1.04
385 pm = 3.85*10^(-8) cm
The volume of the unit cell is the cube of that, which is 5.71*10^(-23) cm^3. Since the ratio of mass to volume (i.e. the density) must be the same no matter what amount of TlCl you have, you can say:
7 = x/(5.71*10^(-23)), where x is the mass of the unit cell. Solving for x, you get 4*10^(-22) g.
The mass of a molecule of TlCl is 240 amu, which in grams is 4*10^(-22) g. The mass of the unit cell and the mass of a molecule of TlCl is the same. Therefore there is one formula unit of TlCl per unit cell.
Sodium chlorate decomposes into sodium chloride and oxygen.
The reaction is
NaClO3 --Δ--> NaCl + O2
The Δ means that heat is used
This equation is still not balanced.
Balancing the equation
2NaClO3 --Δ--> 2NaCl + 3O2
The equation is now balanced.