What type of igneous rock has large crystals

Determine the rate law, including the values of the orders and rate law constant, for the following reaction using the experimen

olga55 [171]

Answer: Rate law= $k[A]^1[B]^2$ , order with respect to A is 1, order with respect to B is 2 and total order is 3. Rate law constant is $3L^2mol^{-2}s^{-1}$

Explanation: Rate law says that rate of a reaction is directly proportional to the concentration of the reactants each raised to a stoichiometric coefficient determined experimentally called as order.

$Rate=k[A]^x[B]^y$

k= rate constant

x = order with respect to A

y = order with respect to A

n = x+y = Total order

a) From trial 1: $1.2\times 10^{-2}=k[0.10]^x[0.20]^y$ (1)

From trial 2: $4.8\times 10^{-2}=k[0.10]^x[0.40]^y$ (2)

Dividing 2 by 1 : $\frac{4.8\times 10^{-2}}{1.2\times 10^{-2}}=\frac{k[0.10]^x[0.40]^y}{k[0.10]^x[0.20]^y}$

$4=2^y,2^2=2^y$ therefore y=2.

b) From trial 2: $4.8\times 10^{-2}=k[0.10]^x[0.40]^y$ (3)

From trial 3: $9.6\times 10^{-2}=k[0.20]^x[0.40]^y$ (4)

Dividing 4 by 3: $\frac{9.6\times 10^{-2}}{4.8\times 10^{-2}}=\frac{k[0.20]^x[0.40]^y}{k[0.10]^x[0.40]^y}$

$2=2^x,2=2^1$ , x=1

Thus rate law is $Rate=k[A]^1[B]^2$

Thus order with respect to A is 1 , order with respect to B is 2 and total order is 1+2=3.

c) For calculating k:

Using trial 1: $1.2\times 10^{-2}=k[0.10]^1[0.20]^2$

$k=3 L^2mol^{-2}s^{-1}$ .

6 0

3 years ago

You are requested to reduce the size of 50 ton/hr of a given solid. The size of the feed is such 80% passes a 4-in (76.2 mm) scr

defon

Answer:

1) The power needed to process 50 ton/hr is 135.4 HP.

2) The void fraction of the bed is 0.37.

Explanation:

1) For this type of milling operations, we can estimate the power needed for an operation according to the work index (Ei), the passing size of the circuit feed (F80) and the passing size of the product (P80).

We assume the units of Ei are kWh/t.

The equation that relates this parameters and the power is (size of particles in μm):

$W=Ei*(\frac{10}{\sqrt{P80}} -\frac{10}{\sqrt{F80}} )\\\\W=9.45*(\frac{10}{\sqrt{3175\mu m}} -\frac{10}{\sqrt{76200mm}} )\\\\\\W=9.45*(0.1774+0.0362)=2.019 kWh/t$

The power needed to process 50 ton/hor is

$P=2.0194\frac{kWh}{Ton}*\frac{50Ton}{h}*\frac{1.341HP}{1kW}= 135.4 \, HP$

2) The density of the packed bed can be expressed as

$\rho=f_v*\rho_v+f_s*\rho_s$

being f the fraction and ρ the density of every fraction. We know that the density of the void is 0 (ρv=0) and that fv=1-fs (the sum of the fractions ois equal to the total space).

Then we can rearrange

$\rho=f_v*\rho_v+f_s*\rho_s\\\\\rho=f_v*0+(1-f_v)*\rho_s\\\\\rho/\rho_s=1-f_v\\\\f_v=1-\rho/\rho_s=1-990/1570=1-0.63=0.37$