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puteri [66]
3 years ago
15

How is an oxidation half-reaction written using the reduction potential chart? How is the oxidation potential voltage determined

?
Chemistry
2 answers:
insens350 [35]3 years ago
7 0
Oxidation  half  reaction  is  written   as    follows when  using  using  reduction potential  chart
example  when  using  copper  it is  written  as  follows
CU2+   +2e-  --> c(s)  +0.34v
 oxidasation  is the  loos  of  electron  hence copper oxidation  potential  is  as  follows
cu (s)  -->  CU2+   +2e    -0.34v

Veronika [31]3 years ago
5 0

Answer:

Oxidation half reaction is the reverse of the reaction depicted in the chart and the oxidation potential will have the opposite sign relative to that in the chart

Explanation:

Redox reactions i.e. reduction-oxidation reactions generally involve transfer of electrons between two species.

Reduction half reaction involves the gain of electrons whereas oxidation half reactions involve the loss of electrons. For example

Oxidation: Loss of electrons

A\rightarrow A^{+} + e^{-}

Reduction: Gain of electrons

A^{+}+e^{-}\rightarrow A

A reduction potential chart gives the standard reduction potential of various species in terms of the reduction half reaction.

For example, in the case of Zn, the standard reduction potential value (E⁰) would be:

Zn^{+}+2e^{-}\rightarrow Zn       E0(reduction) =-0.76 V

The corresponding oxidation reaction and potential would be the reverse of the above reaction:

Zn\rightarrow Zn^{+}+2e^{-}        E0(oxidation) =+0.76 V

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Nicotine, a component of tobacco, is composed of C, H, and N. A 7.875-mg sample of nicotine was combusted, producing 21.363 mg o
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Answer: The empirical formula for the given compound is C_5H_7N

Explanation:

The chemical equation for the combustion of compound having carbon, hydrogen, and nitrogen follows:

C_xH_yN_z+O_2\rightarrow CO_2+H_2O

where, 'x', 'y' and 'z' are the subscripts of carbon, hydrogen and nitrogen respectively.

We are given:

Mass of CO_2=21.363mg=21.363\times 10^3g=21363g

Mass of H_2O=6.125g=6.125\times 10^3g=6125g

We know that:

Molar mass of carbon dioxide = 44 g/mol

Molar mass of water = 18 g/mol

For calculating the mass of carbon:

In 44 g of carbon dioxide, 12 g of carbon is contained.

So, in 21363 g of carbon dioxide, \frac{12}{44}\times 21363=5826.27g of carbon will be contained.

For calculating the mass of hydrogen:

In 18 g of water, 2 g of hydrogen is contained.

So, in 6125 g of water, \frac{2}{18}\times 6125=680.55 of hydrogen will be contained.

Now we have to calculate the mass of nitrogen.

Mass of nitrogen in the compound = (7875) - (5826.27 + 680.55) = 1368.18 g

To formulate the empirical formula, we need to follow some steps:

Step 1: Converting the given masses into moles.

Moles of Carbon =\frac{\text{Given mass of Carbon}}{\text{Molar mass of Carbon}}=\frac{5826.27g}{12g/mole}=485.52moles

Moles of Hydrogen = \frac{\text{Given mass of Hydrogen}}{\text{Molar mass of Hydrogen}}=\frac{680.55g}{1g/mole}=680.55moles

Moles of Nitrogen = \frac{\text{Given mass of nitrogen}}{\text{Molar mass of nitrogen}}=\frac{1368.18g}{14g/mole}=97.73moles

Step 2: Calculating the mole ratio of the given elements.

For the mole ratio, we divide each value of the moles by the smallest number of moles calculated which is 0.0154 moles.

For Carbon = \frac{485.52}{97.73}=4.96\approx 5

For Hydrogen  = \frac{680.55}{97.73}=6.96\approx 7

For Nitrogen = \frac{97.73}{97.73}=1

Step 3: Taking the mole ratio as their subscripts.

The ratio of C : H : N = 5 : 7 : 1

Hence, the empirical formula for the given compound nicotine is C_5H_7N_1=C_5H_7N

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