At what the pressure, in atmospheres, that O2, gas at 75°C has a density of 2.00 g/L

The equilibrium constant Kc for the reaction below is 0.00584 at a certain temperature. Br2(g) ⇌ 2Br(g) If the initial concentra

Vinil7 [7]

Answer:

Explanation:

Given that:

The chemical equation for the reaction is:

Br2(g) ⇌ 2Br(g)

Initially 0.0345M 0.0416M

$Q_C = \dfrac{[Br]^2}{[Br_2]} = \dfrac{(0.0416)^2}{(0.0345)}= 0.05016$

$Q_C =0.05016 >>> K_c(0.00584)$

Thus, the given reaction will proceed in the backward direction

The I.C.E table is as follows:

Br2(g) ⇌ 2Br(g)

I 0.0345 0.0416

C +x -2x

E (0.0345+x) (0.0416 -2x)

$K_c = \dfrac{[Br]^2}{[Br_2]} = \dfrac{(0.0416-2x)^2}{(0.0345+x)} = 0.00584$

= 0.00173056 - 0.0832x - 0.0832x + 4x² = 0.00584 (0.0345 +x)

= 0.00173056 - 0.166x + 4x² = 2.0148× 10⁻⁴ + 0.00584x

= 0.00173056 - 2.0148× 10⁻⁴ - 0.166x - 0.00584x + 4x²

= 0.00152908 - 0.17184x + 4x²

Solving by using Quadratic formula

x = 0.03038 or 0.0126

For x = 0.03038

At equilibrium

[Br₂] = (0.0345 + 0.03038) = 0.06488 M

[Br] = (0.0416 -2(0.03038)) = - 0.01916 M

Since we have a negative value for [Br], we discard the value for x

For x = 0.0126

At equilibrium

[Br₂] = (0.0345 + 0.0126) = 0.0471 M

[Br] = (0.0416 -2(0.0126)) = 0.0164 M

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A 0.175 M solution of an enantiomerically pure chiral compound D has an observed rotation of +0.27° in a 1-dm sample

-BARSIC- [3]

Answer:

The specific rotation of D is 11.60° mL/g dm

Explanation:

Given that:

The path length (l) = 1 dm

Observed rotation (∝) = + 0.27°

Molarity = 0.175 M

Molar mass = 133.0 g/mol

Concentration in (g/mL) = 0.175 mol/L × 133.0 g/mol

Concentration in (g/mL) = 23.275 g/L

Since 1 L = 1000 mL

Concentration in (g/mL) = 0.023275 g/mL

The specific rotation [∝] = ∝/(1×c)

= 0.27°/( 1 dm × 0.023275 g/mL )

= 11.60° mL/g dm

Thus, the specific rotation of D is 11.60° mL/g dm

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At what the pressure, in atmospheres, that O2, gas at 75°C has a density of 2.00 g/L​

At what the pressure, in atmospheres, that O2, gas at 75°C has a density of 2.00 g/L