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Eva8 [605]
3 years ago
12

Phenolphthalein has a pka of 9.7 and is colorless in its acid form and pink in its basic form. part a for ph= 2.0 calculate [in−

]/[hin].
Chemistry
2 answers:
Tresset [83]3 years ago
8 0

Answer:

1.9953 × 10⁻⁸

Explanation:

Considering the Henderson- Hasselbalch equation for the calculation of the pH of the indicator as:

pH = pKa + log[In⁻]/[HIn]

Where Ka is the dissociation constant of the acid.

Given, pKa = 9.7

pH = 2.0

So,  

2.0 = 9.7 + log[In⁻]/[HIn]

log[In⁻]/[HIn]  = - 7.7

<u>[In⁻]/[HIn] = Antilog (-7.7) = 1.9953 × 10⁻⁸</u>

Karo-lina-s [1.5K]3 years ago
4 0
Use the h-h equation! 

pH = pKa + log[In-/HIn]
2.0 = 9.7 + log[In-/HIn]
-7.7 = log[In-/HIn]
10^-7.7 = [In-/HIn]
[In-/HIn] = 1.995 x 10^-8

Hope this helps!
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A reaction mixture initially contains 0.140 MCO and 0.140 MH2O. What will be the equilibrium concentration of CO?
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Answer:

0.013 M

Explanation:

From the question, we can make the following deductions; we are given mixture that contains two compounds, that is A and B, 0.140 M CO and 0.140 M H2O respectively. Then, we are asked to find the equilibrium concentration of Carbonmonoxide,CO.

So, the equation for the reaction is given below;

CO + H2O <-----------------> CO2 + H2.

Initially: we have 0.14M of CO, 0.14M of H2O and zero (0) concentration of CO2 and H2.

At time,t = CO =0.14 - x , H2O = 0.14 - x, CO2 and H2 = x.

The above reaction consist of the forward reaction and the backward reaction.

Therefore, the equilibrium Concentration of CO;

(Since we are giving that Kc = 102). Then, Kc=  [CO2][H2] ÷ [CO][H2O]. Where Kc is the equilibrium constant.

Therefore, 102 = [x^2] / [0.14 - x]^2.

==> 10.1= x/0.14 - x.

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x + 10.1 x = 0.141.

===> 11.1 x = 0.141.

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8 0
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Answer:

See explanation

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Morality = 0.1 m

But

∆T= K × i × m

Where ∆T = boiling point elevation

i= number of particles (this is equal to 1 because naphthalene is molecular and not ionic)

m= molality of naphthalene = 0.1 m

K= boiling point elevation constant = 5.12 °C/m

∆T= 5.12 °C/m ×0.1 = 0.512°C

For freezing point depression

∆T= K× i × m

Where ∆T= freezing point depression

i= number of particles (this is equal to 1 because naphthalene is molecular and not ionic)

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From Raoult's law;

∆P = XBPA°

Where;

∆P = vapour pressure lowering

XB = mole fraction of solute

PA° = vapour pressure of pure solvent

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Therefore;

∆P = 0.0077 × 100torr = 0.77 torr

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∆P = 0.77 torr

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