The most stable conformation of 3-isopropyl-1,1dimethylcyclohexane equatorial ethyl group (more stable). The stability of ethylcyclohexane's equatorial conformer exceeds that of its axial conformer by 7.4 kJ/mol.
According to the previous section, the chair conformation with the equatorial methyl group is more stable because it reduces steric repulsion, and as a result, the equilibrium favors the more stable conformer. Strongly favoring the equatorial shape is methylcyclohexane. The methyl group is in close proximity to the axial hydrogens in the axial conformation, which has an energetically unfavorable effect known as a 1,3-diaxial interaction. The methyl group prefers the equatorial shape as a result. The conformation of ethylcyclohexane in which the ethyl group is in the equatorial position is the most stable.
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