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Sergeu [11.5K]
3 years ago
5

2 HI(g) ⇄ H2(g) + I2(g) Kc = 0.0156 at 400ºC 0.550 moles of HI are placed in a 2.00 L container and the system is allowed to rea

ch equilibrium. Calculate the concentration of H2 at equilibrium. 0.0275 M (Your correct answer) 0.138 M 0.275 M 0.550 M 0.220 M
Chemistry
1 answer:
Alex_Xolod [135]3 years ago
4 0

<u>Answer:</u> The concentration of hydrogen gas at equilibrium is 0.0275 M

<u>Explanation:</u>

Molarity is calculated by using the equation:

\text{Molarity}=\frac{\text{Number of moles}}{\text{Volume of solution (in L)}}

Moles of HI = 0.550 moles

Volume of container = 2.00 L

\text{Initial concentration of HI}=\frac{0.550}{2}=0.275M

For the given chemical equation:

                          2HI(g)\rightleftharpoons H_2(g)+I_2(g)

<u>Initial:</u>                  0.275

<u>At eqllm:</u>           0.275-2x      x         x

The expression of K_c for above equation follows:

K_c=\frac{[H_2][I_2]}{[HI]^2}

We are given:

K_c=0.0156

Putting values in above expression, we get:

0.0156=\frac{x\times x}{(0.275-2x)^2}\\\\x=-0.0458,0.0275

Neglecting the negative value of 'x' because concentration cannot be negative

So, equilibrium concentration of hydrogen gas = x = 0.0275 M

Hence, the concentration of hydrogen gas at equilibrium is 0.0275 M

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Answer:

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Now solving for b:

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(V-nb)=\frac{nRT}{(P+\frac{n^{2}a}{V^{2}})}

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