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forsale [732]
3 years ago
7

A 2.00-g sample of a large biomolecule was dissolved in 15.0 g carbon tetrachloride. the boiling point of this solution was dete

rmined to be 77.85c. calculate the molar mass of the biomolecule. for carbon tetrachloride, the boiling-point constant is 5.03c kg/mol, and the boiling point of pure carbon tetrachloride is 76.50c.
Chemistry
1 answer:
Katarina [22]3 years ago
5 0
We will use boiling point formula:

ΔT = i Kb m 

when ΔT is the temperature change from the pure solvent's boiling point to the boiling point of the solution = 77.85 °C - 76.5 °C = 1.35

and Kb is the boiling point constant =5.03

and m = molality 

i = vant's Hoff factor

so by substitution, we can get the molality:

1.35 = 1 * 5.03 * m

∴ m = 0.27

when molality = moles / mass  Kg

           0.27 = moles /  0.015Kg

∴ moles = 0.00405 moles

∴ The molar mass = mass / moles
                               = 2 g /  0.00405 moles 
                               = 493.8 g /mol
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___________ a mixture of iron filings and sulfur will make the iron and sulfur atoms combine chemically
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5 0
3 years ago
Read 2 more answers
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Kryger [21]

The empirical formula : C₁₂H₄F₇

The molecular formula : C₂₄H₈F₁₄

<h3>Further explanation</h3>

mol C (MW=12 g/mol)

\tt \dfrac{18.24}{12}=1.52

mol H(MW=1 g/mol) :

\tt \dfrac{0.51}{1}=0.51

mol F(MW=19 g/mol)

\tt \dfrac{16.91}{19}=0.89

mol ratio of C : H : O =1.52 : 0.51 : 0.89=3 : 1 : 1.75=12 : 4 : 7

Empirical formula : C₁₂H₄F₇

(Empirical formula)n=molecular formula

( C₁₂H₄F₇)n=562 g/mol

(12.12+4.1+7.19)n=562

(281)n=562⇒ n =2

Molecular formula : C₂₄H₈F₁₄

6 0
3 years ago
A series of six solutions was prepared at the given concentrations. Sample A B C D E F Concentration (mM) 50 100 150 200 300 400
ioda

Answer:

300 mM

Explanation:

In order to solve this problem we need to calculate the line of best fit for those experimental values. The absorbance values go in the Y-axis while the concentration goes in the X-axis. We can calculate the linear fit using Microsoft Excel using the LINEST function (alternatively you can write the Y data in one column and X data in another one, then use that data to create a dispersion graph and finally add the line of best fit and its formula).

The <u>formula for the line of best fit for this set of data is</u>:

  • y = 0.005 * x

So now we <u>calculate the value of </u><u><em>x</em></u><u> when </u><u><em>y</em></u><u> is 1.50</u>:

  • 1.50 = 0.005 * x
  • x = 300 mM

7 0
3 years ago
The following questions pertain to a system contains 122 g CO(g) in a 0.400 L container at -71.2 degrees C.
7nadin3 [17]

Answer:

a. P = 182 atm

Explanation:

Data Given:

amount of CO = 122g

Volume of CO = .400 L

Temperature of CO =  -71.2°C

Convert the temperature to Kelvin

T = °C + 273

T =  -71.2 + 273

T =  201.8 K

a. Calculate the pressure exerted by the CO(g) in this system using the ideal gas equation (P) = ?

Solution:

To calculate Pressure by using ideal gas formula

                  PV = nRT

Rearrange the equation for Pressure

                   P = nRT / V . . . . . . . . . (1)

where

P = pressure

V = Volume

T= Temperature

n = Number of moles

R = ideal gas constant = 0.08206 L.atm / mol. K

For this we have to know the mole of the gas and the following formula will be used

                 no. of moles = mass in grams / molar mass . . . . . . (2)

Molar mass of CO = 12 + 16 = 28 g/mol

Put values in equation 2

                no. of moles = 122 g / 28 g/mol

                no. of moles = 4.4 mol

Now put the value in formula (1) to calculate Pressure for CO

P = 4.4 x 201.8 K x 0.08206 (L.atm/mol. K) / 0.400 L

P = 182 atm

So the pressure will be 182 atm

__________

b. Data Given:

Actual pressure exerted by CO = 145 atm

expected pressure exerted by CO = 182 atm

why the actual pressure is less than what would be expected = ?

Explanation:

This is because of the deviation from ideal behavior of real gases.

The real gases approach to ideal behavior under very high temperature and very low pressure.

But CO deviate from ideal behavior to give expected value for pressure, because it behave at high pressure and low temperature.

This non-ideal behavior is due to two postulate of ideal behavior

  • gas molecules have negligible volume
  • Gas molecules have negligible inter-molecular interaction

but these postulates not obeyed under real condition. so we calculated the pressure using ideal condition values for gas and obtained the expected value for pressure but the actual pressure value was detected under normal condition.

8 0
3 years ago
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