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Serjik [45]
3 years ago
5

A tank has a volume of 0.1 m3 and is filled with He gas at a pressure of 5 x 106 Pa. A second tank has a volume of 0.15 m' and i

s filled with He gas at a pressure of 6 x 106 Pa. A valve connecting the two tanks is opened. Assumıng He to be a monatomic ideal gas and the walls of the tanks to be adiabatic and rigıd, find the final pressure of the system Hint: Note that the internal energy is constant.
Chemistry
1 answer:
GarryVolchara [31]3 years ago
5 0

Answer:

P=5.6*10^{6} Pa

Explanation:

Consider that, as the system is adiabatic, U_{1}= U_{2} where U1 and U2 are the internal energies before the process and after that respectively.

Consider that: U=H-PV, and that the internal energy of the first state is the sum of the internal energy of each tank.

So, H_{1}-P_{1}V_{1}=H_{2}-P_{2}V_{2}\\H_{1}^{A} -P_{1}^{A}V_{1}^{A}+H_{1}^{B} -P_{1}^{B}V_{1}^{B}=H_{2}-P_{2}V_{2}

Where A y B are the tanks. The enthalpy for an ideal gas is only function of the temperature, as the internal energy is too; so it is possible to assume: H_{1}=H_{2}\\H_{1}^{A}+H_{1}^{B} =H_{2}

So, P_{1}^{A}V_{1}^{A}+P_{1}^{B}V_{1}^{B}=P_{2}V_{2}

Isolating P_{2},

P_{2}=\frac{P_{1}^{A}V_{1}^{A}+P_{1}^{B}V_{1}^{B}}{V_{2}}

V_{2}=V_{1}^{A}+V_{1}^{B}=0.25m^{3}

So,

P_{2}=\frac{5000000*0.1+6000000*0.15}{0.25}=5600000Pa=5.6*10^{6} Pa

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Explanation:

Given that:

The activation energy of a certain uncatalyzed biochemical reaction is 50.0 kJ/mol,

Let the activation energy for a catalyzed biochemical reaction = E₁

E₁ = ??? (unknown)

Let the activation energy for an uncatalyzed biochemical reaction = E₂

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Temperature (T) = 37°C

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Rate constant (R) = 8.314 J/mol/k

Also, let the constant rate for the catalyzed biochemical reaction = K₁

let the constant rate for the uncatalyzed biochemical reaction = K₂

If the  rate constant for the reaction increases by a factor of 3.50 × 10³ as compared with the uncatalyzed reaction, That implies that:

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we can use the formula for Arrhenius equation;

K=Ae^{\frac{-E}{RT}}

If K_1=Ae^{\frac{-E_1}{RT}} -------equation 1     &

K_2=Ae^{\frac{-E_2}{RT}} -------equation 2

\frac{K_1}{K_2} = e^{\frac{-E_1-E_2}{RT}

E_1= E_2-RT*In(\frac{K_1}{K_2})

E_1= 50,000-8.314*310.15*In(\frac{3.50*10^3}{1})

E_1 = 28957.39292  J/mol

E₁ ≅ 28.96 kJ/mol

∴ the activation energy for a catalyzed biochemical reaction (E₁) = 28.96 kJ/mol

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