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DanielleElmas [232]
3 years ago
7

You are given solutions of hcl and naoh and must determine their concentrations. you use 27.5 ml of naoh to titrate 100.0 ml of

hcl and 18.4 ml of naoh to titrate 50.0 ml of 0.0782 m h2so4. based on this data, what were the concentrations (molarities) of the hcl and naoh solutions, respectively
Chemistry
1 answer:
Dafna1 [17]3 years ago
3 0
1) Start by standardizing the solution of NaOH by using the solution of H2SO4 whose concentration is known.

2) Equation:

2Na OH + H2SO4 --> Na2 SO4 + 2H2O

3) molar ratios

2 mol NaOH : 1 mol H2SO4

4) Number of moles of H2SO4 in 50.0 ml of 0.0782 M solution

M = n / V => n = M*V = 0.0782 M * 0.050 l = 0.00391 mol H2SO4

5) Number of moles of NaOH

2 moles NaOH / 1mol H2SO4 * 0.00391 mol H2SO4 = 0.00782 mol NaOH

6) Concentration of the solution of NaOH

M = n / V = 0.00782 mol / 0.0184 ml = 0.425 M

7) Standardize the solution of HCl

Chemical reaction:

NaOH + HCl --> NaCl + H2O

8) Molar ratios

1 mol NaOH : 1 mol HCl

9) Number of moles of NaOH in 27.5 ml

M = n / V => n = M * V = 0.425 M * 0.0275 l = 0.01169 moles NaOH

10) Number of moles of HCl

1 mol HCl / 1mol NaOH * 0.01169 mol NaOH = 0.01169 mol HCl

11) Concentration of the solution of HCl

M = n / V = 0.01169 mol / 0.100 l = 0.1169 M

Rounded to 3 significant figures = 0.117 M

Answers:

[NaOH] = 0.425 M
[HCl] = 0.117 M
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A mixture containing 0.477 mol he(g), 0.265 mol ne(g), and 0.115 mol ar(g) is confined in a 7.00-l vessel at 25 ∘c. part a calcu
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Q1)
we can use the ideal gas law equation to find the total pressure of the system ;
PV = nRT
where P - pressure
V - volume - 7 x 10⁻³ m³
n - number of moles 
total number of moles - 0.477 + 0.265 + 0.115 = 0.857 mol
R - universal gas constant - 8.314 Jmol⁻¹K⁻¹
T - temperature in K - 273 + 25 °C = 298 K
substituting the values in the equation 
 P x 7 x 10⁻³ m³ = 0.857 mol x 8.314 Jmol⁻¹K⁻¹ x 298 K
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Q2)
partial pressure is the pressure exerted by the individual gases in the mixture.
partial pressure for each gas can be calculated by multiplying the total pressure by mole fraction of the individual gas.

total number of moles - 0.477 + 0.265 + 0.115 = 0.857 mol
mole fraction of He - \frac{0.477}{0.857}  = 0.557
mole fraction of Ne - \frac{0.265}{0.857} =   0.309
mole fraction of Ar - \frac{0.115}{0.857}  = 0.134
partial pressure - total pressure x mole fraction
partial pressure of He - 2.99 atm x 0.557 = 1.67 atm
partial pressure of Ne - 2.99 atm x 0.309 = 0.924 atm
partial pressure of Ar - 2.99 atm x 0.134 = 0.401 atm
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