Answer:
x = 100 * 1.1897 = 118.97 %, which is > 100 meaning that all of the HClO2 dissociates
Explanation:
Recall that , depression present in freezing point is calculated with the formulae = solute particles Molarity x KF
0.3473 = m * 1.86
Solving, m = 0.187 m
Moles of HClO2 = mass / molar mass = 5.85 / 68.5 = 0.0854 mol
Molality = moles / mass of water in kg = 0.0854 / 1 = 0.0854 m
Initial molality
Assuming that a % x of the solute dissociates, we have the ICE table:
HClO2 H+ + ClO2-
initial concentration: 0.0854 0 0
final concentration: 0.0854(1-x/100) 0.0854x/100 0.0854x / 100
We see that sum of molality of equilibrium mixture = freezing point molality
0.0854( 1 - x/100 + x/100 + x/100) = 0.187
2.1897 = 1 + x / 100
x = 100 * 1.1897 = 118.97 %, which is > 100 meaning that all of the HClO2 dissociates
I think it might just might be e
avogadros law states that under constant temp n pressure, volume of a gas is directly proportional to amount of gas
amount of gas1 = 352millimoles
amount of gas2 = 352+100 = 452millimoles
new vol = old vol x 452/352 = 25.2 x 452/352
= 32.4 mL
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