the reagents necessary to convert alcohol to ketone which involves oxidation of alcohols.
<h3>
What is oxidation of alcohols?</h3>
- Alcohol oxidation is a significant organic chemistry process. Secondary alcohols can be oxidized to produce ketones, while primary alcohols can be oxidized to produce aldehydes and carboxylic acids.
- In contrast, tertiary alcohols cannot be oxidized without the C-C bonds in the molecule being broken.
- In order to cause primary alcohols to oxidize into aldehydes
- (dichromate)
- /pyridine (Collins reagent)
- Chromium pyridinium compound (PCC)
- Dichromate of pyridinium (PDC, Cornforth reagent)
- Periodinane by Dess-Martin
- Oxalyl chloride with dimethylsulfoxide (DMSO) for Swern
- oxidation of secondary alcohols to ketones
- (dichromate)
- /pyridine (Collins reagent)
- Chromium pyridinium compound (PCC)
- Dichromate of pyridinium (PDC, Cornforth reagent)
- Periodinane by Dess-Martin
- Oxalyl chloride and dimethyl sulfoxide (DMSO) (Swern oxidation)
- /acetone (Jones oxidation)
- Acetone with aluminum isopropoxide (Oppenauer oxidation)
To learn more about oxidation of alcohols with the given link
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<u>Question:</u>
Identify the reagents necessary to achieve each of the following transformations
The answer is both B and C
positive chromic acid test is indicated by disappearance of orange colour from chromic ions and appearance of blue-green color from Chromium (iii) ion (reduction of chromium ion from CrO4 - to Cr3+)
positive chromic test indicated functional groups that can be oxidized.
cyclohexanol can be oxidized to become cyclohexanone
and pentan-3-ol can be oxidized to become pentan-3-one
hence both B and C will show positive chromic acid test
A) tert butanol although contains alcohol functional group, cannot be further oxidized as it is a tertiary alcohol
Answer:
A solid's particles are packed closely together. The forces between the particles are strong enough that the particles cannot move freely; they can only vibrate. As a result, a solid has a stable, definite shape and a definite volume. Solids can only change shape under force, as when broken or cut.