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3 years ago

What product is obtained from the aldol condensation of cyclohexanone?

Physics

1 answer:

Evgesh-ka [11]3 years ago

6 0

Answer:

First product is FCH-OH chemically known as 2-[2-furyl(hydroxyl)methyl]-Second product is FCH i.e (2E)-2-[2-furyl-methylene]-cyclohexanone

Explanation:

Please see the attached image for complete chemical reaction of aldol condensation of cyclohexanone

Aldol Condensation is a form of electrophilic substitution reaction in which the alpha carbon in enols or enolate anions is substituted by an electrophile to form carbon-carbon bond. Cyclohexanone also known as the first ketone consists of two alpha-carbons and four potential substitutions i.e alpha-hydrogens but none of the hydrogen on the ring is substituted. Ketones such as cyclohexanone are much more acidic than their parent hydrocarbon.

First product is FCH-OH chemically known as 2-[2-furyl(hydroxyl)methyl]-cyclohexanone that further undergoes dehydration resulting into FCH i.e (2E)-2-[2-furyl-methylene]-cyclohexanone

Based on the explanations above, the compound formed is shown in the image.

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a) Zinc (work function: 4.3 eV)

The equation for the photoelectric effect is:

$E=\phi + K$ (1)

where

$E=\frac{hc}{\lambda}$ is the energy of the incident photon, with

h = Planck constant

c = speed of light

$\lambda$ = wavelength

$\phi$ = work function of the metal

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$eV=K$

So we can rewrite (1) as

$E=\phi + eV$

where we have:

$\lambda=200 nm = 2\cdot 10^{-7} m$

V = 1.93 V

e is the electron charge

First of all, let's find the energy of the incident photon:

$E=\frac{hc}{\lambda}=\frac{(6.63\cdot 10^{-34}Js)(3\cdot 10^8 m/s)}{2\cdot 10^{-7}m}=9.95\cdot 10^{-19} J$

Converting into electronvolts,

$E=\frac{9.95\cdot 10^{-19}J}{1.6\cdot 10^{-19} J/eV}=6.22 eV$

And now we can solve eq.(1) to find the work function of the metal:

$\phi = E-eV=6.22 eV-1.93 eV=4.29 eV$

so, the metal is most likely zinc, which has a work function of 4.3 eV.

b) The stopping potential is still 1.93 V

Explanation:

The intensity of the incident light is proportional to the number of photons hitting the surface of the metal. However, the energy of the photons depends only on their frequency, so it does not depend on the intensity of the light. This means that the term E in eq.(1) does not change.

Moreover, the work function of the metal is also constant, since it depends only on the properties of the material: so $\phi$ is also constant in the equation. As a result, the term (eV) must also be constant, and therefore V, the stopping potential, is constant as well.

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