Consider the change given below. At constant pressure, is work done by the system on the surroundings? By the surroundings on th
1 answer:
Answer : At constant pressure work is done by the system on the surroundings.
Explanation :
Work done : Any quantity that flows across the boundary of a system during a change in its state and it completely convertible into the lifting of a weight in the surroundings.
Formula for work done is:
Sign convention :
- When volume expand then system work that means work done by the system.
w = (-ve)
- When volume compress then surrounding work that means work done on the system.
w = (+ve)
The given reaction is:
This is a evaporation process in which phase changes from liquid state to gaseous state at constant temperature.
At constant pressure, work depends only on volume.
In evaporation process, the volume expand that means work is done by the system on the surroundings.
Sign convention is, w = (-ve)
Thus, at constant pressure work is done by the system on the surroundings.
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<h3>Answer:</h3>
There is One electrophilic center in acetyl chloride.
<h3>Explanation:</h3>Electrophile is defined as any specie which is electron deficient and is in need of electrons to complete its electron density or octet. The main two types of electrophiles are those species which either contain positive charge (i.e. NO₂⁺, Cl⁺, Br⁺ e.t.c) or partial positive charge like that contained by the sp² hybridized carbon of acetyl chloride shown below in attached picture.
In acetyl chloride the partial positive charge on sp² hybridized carbon is generated due to its direct bonding to highly electronegative elements *with partial negative charge) like oxygen and chlorine, which tend to pull the electron density from carbon atom making it electron deficient and a good electrophile for incoming nucleophile as a center of attack.