<span>To raise the liquid temperature to the point of boiling take 1231.776 joules of energy. To convert to a gas takes 5320.645 joules. To raise to 108 degrees Celsius takes 1456.848 joules. Total amount of energy needed (as heat) equals 8009.269 joules or 8.009 kj.</span>
Explanation:
A physical change is one that alters the physical properties of matter (particularly the form and state).
A chemical change is one in which new kind of matter is formed. It is always accompanied by energy changes (evolution or absorption of energy in form of heat or light or both).
Now, the salient differences between physical and chemical changes;
- Physical changes are easily reversible whereas chemical changes are not easily reversible.
- Physical changes lead to the production of no new kinds of matter whereas chemical changes leads to the production of new kinds of matter.
- Physical changes involves no change in mass whereas chemical changes involves change in mass.
- Physical changes require little energy whereas considerable amount of energy is needed for chemical changes.
Answer:
5.0 x 10⁹ years.
Explanation:
- It is known that the decay of a radioactive isotope isotope obeys first order kinetics.
- Half-life time is the time needed for the reactants to be in its half concentration.
- If reactant has initial concentration [A₀], after half-life time its concentration will be ([A₀]/2).
- Also, it is clear that in first order decay the half-life time is independent of the initial concentration.
- The half-life of K-40 = 1.251 × 10⁹ years.
- For, first order reactions:
<em>k = ln(2)/(t1/2) = 0.693/(t1/2).</em>
Where, k is the rate constant of the reaction.
t1/2 is the half-life of the reaction.
∴ k =0.693/(t1/2) = 0.693/(1.251 × 10⁹ years) = 5.54 x 10⁻¹⁰ year⁻¹.
- Also, we have the integral law of first order reaction:
<em>kt = ln([A₀]/[A]),</em>
where, k is the rate constant of the reaction (k = 5.54 x 10⁻¹⁰ year⁻¹).
t is the time of the reaction (t = ??? year).
[A₀] is the initial concentration of (K-40) ([A₀] = 100%).
[A] is the remaining concentration of (K-40) ([A] = 6.25%).
∴ (5.54 x 10⁻¹⁰ year⁻¹)(t) = ln((100%)/( 6.25%))
∴ (5.54 x 10⁻¹⁰ year⁻¹)(t) = 2.77.
∴ t = 2.77/(5.54 x 10⁻¹⁰ year⁻¹) = 5.0 x 10⁹ years.
Answer : The activation energy of the reaction is, 
Solution :
The relation between the rate constant the activation energy is,
![\log \frac{K_2}{K_1}=\frac{Ea}{2.303\times R}\times [\frac{1}{T_1}-\frac{1}{T_2}]](https://tex.z-dn.net/?f=%5Clog%20%5Cfrac%7BK_2%7D%7BK_1%7D%3D%5Cfrac%7BEa%7D%7B2.303%5Ctimes%20R%7D%5Ctimes%20%5B%5Cfrac%7B1%7D%7BT_1%7D-%5Cfrac%7B1%7D%7BT_2%7D%5D)
where,
= initial rate constant = 
= final rate constant = 
= initial temperature = 
= final temperature = 
R = gas constant = 8.314 kJ/moleK
Ea = activation energy
Now put all the given values in the above formula, we get the activation energy.
![\log \frac{8.75\times 10^{-3}L/mole\text{ s}}{4.55\times 10^{-5}L/mole\text{ s}}=\frac{Ea}{2.303\times (8.314kJ/moleK)}\times [\frac{1}{468K}-\frac{1}{531K}]](https://tex.z-dn.net/?f=%5Clog%20%5Cfrac%7B8.75%5Ctimes%2010%5E%7B-3%7DL%2Fmole%5Ctext%7B%20s%7D%7D%7B4.55%5Ctimes%2010%5E%7B-5%7DL%2Fmole%5Ctext%7B%20s%7D%7D%3D%5Cfrac%7BEa%7D%7B2.303%5Ctimes%20%288.314kJ%2FmoleK%29%7D%5Ctimes%20%5B%5Cfrac%7B1%7D%7B468K%7D-%5Cfrac%7B1%7D%7B531K%7D%5D)
Therefore, the activation energy of the reaction is,
