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Leya [2.2K]
3 years ago
14

What is the general form for the simplest type of acid-base reaction?

Chemistry
1 answer:
omeli [17]3 years ago
5 0
HA +BOH→BA+H2O neutralisation reaction for monobasic acid monoacidic base
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A titration of 25.0 mL of a solution of the weak base aniline, C6H5NH2, requires 25.67 mL of 0.175 M HCl to reach the equivalenc
Lorico [155]

Answer:

a. 0.180M of C₆H₅NH₂

b. 0.0887M C₆H₅NH₃⁺

c. pH = 2.83

Explanation:

a. Based in the chemical equation:

C₆H₅NH₂(aq) + HCl(aq) → C₆H₅NH₃⁺(aq) + Cl⁻(aq)

<em>1 mole of aniline reacts per mole of HCl</em>

Moles required to reach equivalence point are:

Moles HCl = 0.02567L ₓ (0.175mol / L) = 4.492x10⁻³ moles HCl = moles C₆H₅NH₂

As the original solution had a volume of 25.0mL = 0.0250L:

4.492x10⁻³ moles C₆H₅NH₂ / 0.0250L = 0.180M of C₆H₅NH₂

b. At equivalence point, moles of C₆H₅NH₃⁺ are equal to initial moles of C₆H₅NH₂, that is 4.492x10⁻³ moles

But now, volume is 25.0mL + 25.67mL = 50.67mL = 0.05067L. Thus, molar concentration of C₆H₅NH₃⁺ is:

[C₆H₅NH₃⁺] = 4.492x10⁻³ moles / 0.05067L = 0.0887M C₆H₅NH₃⁺

c. At equivalence point you have just 0.0887M C₆H₅NH₃⁺ in solution. C₆H₅NH₃⁺ has as equilibrium in water:

C₆H₅NH₃⁺(aq) + H₂O(l) → C₆H₅NH₂ + H₃O⁺

Where Ka = Kw / Kb = 1x10⁻¹⁴ / 4.0x10⁻¹⁰ =

<em>2.5x10⁻⁵ = [C₆H₅NH₂] [H₃O⁺] / [C₆H₅NH₃⁺]</em>

When the system reaches equilibrium, molar concentrations are:

[C₆H₅NH₃⁺] = 0.0887M - X

[C₆H₅NH₂] = X

[H₃O⁺] = X

Replacing in Ka formula:

2.5x10⁻⁵ = [X] [X] / [0.0887M - X]

2.2175x10⁻⁶ - 2.5x10⁻⁵X = X²

0 = X² + 2.5x10⁻⁵X - 2.2175x10⁻⁶

Solving for X:

X = -0.0015 → False solution. There is no negative concentrations.

X = 0.001477 → Right solution.

As [H₃O⁺] = X, [H₃O⁺] = 0.001477

Knowing pH = -log [H₃O⁺]

pH = -log 0.001477

<h3>pH = 2.83</h3>

7 0
3 years ago
What does I stand for?
tatuchka [14]
I: Current
V: Voltage
R: resistance
you’re welcome ;)
7 0
3 years ago
Read 2 more answers
Th e molar absorption coeffi cient of a substance dissolved in water is known to be 855 dm3 mol−1 cm−1 at 270 nm. To determine t
Olegator [25]

Answer : The percentage reduction in intensity is 79.80 %

Explanation :

Using Beer-Lambert's law :

A=\epsilon \times C\times l

A=\log \frac{I_o}{I}

\log \frac{I_o}{I}=\epsilon \times C\times l

where,

A = absorbance of solution

C = concentration of solution = 3.25mmol.dm^{3-}=3.25\times 10^{-3}mol.dm^{-3}

l = path length = 2.5 mm = 0.25 cm

I_o = incident light

I = transmitted light

\epsilon = molar absorptivity coefficient = 855dm^3mol^{-1}cm^{-1}

Now put all the given values in the above formula, we get:

\log \frac{I_o}{I}=(855dm^3mol^{-1}cm^{-1})\times (3.25\times 10^{-3}mol.dm^{-3})\times (0.25cm)

\log \frac{I_o}{I}=0.6947

\frac{I_o}{I}=10^{0.6947}=4.951

If we consider I_o = 100

then, I=\frac{100}{4.951}=20.198

Here 'I' intensity of transmitted light = 20.198

Thus, the intensity of absorbed light I_A = 100 - 20.198 = 79.80

Now we have to calculate the percentage reduction in intensity.

\% \text{reduction in intensity}=\frac{I_A}{I_o}\times 100

\% \text{reduction in intensity}=\frac{79.80}{100}\times 100=79.80\%

Therefore, the percentage reduction in intensity is 79.80 %

3 0
3 years ago
Scientists call an organism that has two diferente alleles for a trait
aleksklad [387]
An organism that has two different alleles for a trait is called heterogeneous
8 0
3 years ago
The enthalpy of neutralization for the reaction of a strong acid with a strong base is −56 kJ/mol of water produced. How much en
denis23 [38]

Answer:

mxmxmxmxmxmxmxnxnsjjsjsjsjs

kskskw

Explanation:

msmsjsjdjdj

make

wokskwkwkwkwjjejesjsjjsjwjwj

6 0
3 years ago
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