4 years ago

2. Jessica did an investigation about the states of matter. As part of the

Chemistry

1 answer:

velikii [3]4 years ago

4 0

She needs to freeze the liquid change it’s physical state

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The estimated heat of vaporization of diethyl ether using the Chen's rule is A. 29.7 KJ/mol B. 33.5 KJ/mol C. 26.4 KJ/mol D. 36.

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Answer:

C. 26.4 kJ/mol

Explanation:

The Chen's rule for the calculation of heat of vaporization is shown below:

$\Delta H_v=RT_b\left [ \frac{3.974\left ( \frac{T_b}{T_c} \right )-3.958+1.555lnP_c}{1.07-\left ( \frac{T_b}{T_c} \right )} \right ]$

Where,

$\Delta H_v$ is the Heat of vaoprization (J/mol)

$T_b$ is the normal boiling point of the gas (K)

$T_c$ is the Critical temperature of the gas (K)

$P_c$ is the Critical pressure of the gas (bar)

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For diethyl ether:

$T_b=307.4\ K$

$T_c=466.7\ K$

$P_c=36.4\ bar$

Applying the above equation to find heat of vaporization as:

$\Delta H_v=8.314\times307.4 \left [ \frac{3.974\left ( \frac{307.4}{466.7} \right )-3.958+1.555ln36.4}{1.07-\left ( \frac{307.4}{466.7} \right )} \right ]$

$\Delta H_v=26400 J/mol$

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1 J = 10⁻³ kJ

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$\Delta H_v=26.4 kJ/mol$

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