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3 years ago

15

If 5750 Joules of energy are added to 455 grams of granite at 24.0 C, what is the final temperature of the granite The specific

heat of granite is 0.79 J/g k

1 answer:

Darina [25.2K]3 years ago

5 0

Joules/ (Grams * Kelvin)
Kelvin = Celsius + 273.15

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If 14c-labeled uracil is added to the growth medium of cells, what macromolecules will be labeled?

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Draw the best lewis structure for bro4- and determine the formal charge on bromine

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Lewis-dot structure : It shows the bonding between the atoms of a molecule and it also shows the unpaired electrons present in the molecule. The electrons are represented by dot.

The given molecule is, perbromate ion.

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Therefore, the total number of valence electrons in perbromate ion, $BrO_4^-$ = 7 + 4(6) + 1 = 32

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$\text{Formal charge}=\text{Valence electrons}-\text{Non-bonding electrons}-\frac{\text{Bonding electrons}}{2}$

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The Lewis-dot structure of perbromate ion is shown below.

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Be sure to answer all parts. The standard enthalpy of formation and the standard entropy of gaseous benzene are 82.93 kJ/mol and

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Answer : The values of $\Delta H^o,\Delta S^o\text{ and }\Delta G^o$ are $33.89kJ,95.94J/K\text{ and }5.299kJ/mol$ respectively.

Explanation :

The given balanced chemical reaction is,

$C_6H_6(l)\rightarrow C_6H_6(g)$

First we have to calculate the enthalpy of reaction $(\Delta H^o)$ .

$\Delta H^o=H_f_{product}-H_f_{reactant}$

$\Delta H^o=[n_{C_6H_6(g)}\times \Delta H_f^0_{(C_6H_6(g))}]-[n_{C_6H_6(l)}\times \Delta H_f^0_{(C_6H_6(l))}]$

where,

$\Delta H^o$ = enthalpy of reaction = ?

n = number of moles

$\Delta H_f^0_{(C_6H_6(g))}$ = standard enthalpy of formation of gaseous benzene = 82.93 kJ/mol

$\Delta H_f^0_{(C_6H_6(l))}$ = standard enthalpy of formation of liquid benzene = 49.04 kJ/mol

Now put all the given values in this expression, we get:

$\Delta H^o=[1mole\times (82.93kJ/mol)]-[1mole\times (49.04J/mol)]$

$\Delta H^o=33.89kJ/mol=33890J/mol$

Now we have to calculate the entropy of reaction $(\Delta S^o)$ .

$\Delta S^o=S_f_{product}-S_f_{reactant}$

$\Delta S^o=[n_{C_6H_6(g)}\times \Delta S^0_{(C_6H_6(g))}]-[n_{C_6H_6(l)}\times \Delta S^0_{(C_6H_6(l))}]$

where,

$\Delta S^o$ = entropy of reaction = ?

n = number of moles

$\Delta S^0_{(C_6H_6(g))}$ = standard entropy of formation of gaseous benzene = 269.2 J/K.mol

$\Delta S^0_{(C_6H_6(l))}$ = standard entropy of formation of liquid benzene = 173.26 J/K.mol

Now put all the given values in this expression, we get:

$\Delta S^o=[1mole\times (269.2J/K.mol)]-[1mole\times (173.26J/K.mol)]$

$\Delta S^o=95.94J/K.mol$

Now we have to calculate the Gibbs free energy of reaction $(\Delta G^o)$ .

As we know that,

$\Delta G^o=\Delta H^o-T\Delta S^o$

At room temperature, the temperature is $25^oC\text{ or }298K$ .

$\Delta G^o=(33890J)-(298K\times 95.94J/K)$

$\Delta G^o=5299.88J/mol=5.299kJ/mol$

Therefore, the values of $\Delta H^o,\Delta S^o\text{ and }\Delta G^o$ are $33.89kJ,95.94J/K\text{ and }5.299kJ/mol$ respectively.

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