Answer:
Xe:[Kr]4d¹⁰5(sp³d³)₆⁺² => Octahedral Geometry (AX₆)⁺²
Explanation:
Xe:[Kr]4d¹⁰(5s²5p₋₁²p₀²p₁²5d₋₂d₋₁d₀)⁺² => Xe[Kr]5(sp³d³)₆²
Ca. #Valence e⁻ = Xe + 6F - 2e⁻ = 1(8) + 6(7) - 2 = 48
Ca. #Substrate e⁻ = 6F = 6(8) = 48
#Nonbonded free pairs e⁻ = (V - S)/2 = (48 - 48)/2 = 0 free pairs
#Bonded pairs e⁻ = 6F substrates = 6 bonded pairs
BPr + NBPr = 6 + 0 = 6 e⁻ pairs => Geometry => [AX₆]⁺² => Octahedron
Xe:[Kr]4d¹⁰(5s²5p₋₁²p₀²p₁²5d₋₂d₋₁d₀)⁺² => Xe[Kr]5(sp³d³)₆⁺²
XeF₆⁺² => 6(sp³d³) hybrid orbitals => Octahedral Geometry (AX₆)
Answer:
Explanation:
In S₈ , there are 8 single bonds which breaks up first . Energy absorbed
= 8 x 240 = 1920 kJ
In S₈ four double bonds of S₂ are formed . Let bond energy be x . In this process energy will be released . energy released in four S₂ molecules formed = 4 x
Given
1920 + 4x = 239
4x = 239 - 1920
x = - 420.25 kJ .
So bond energy of S₂ = 420.25 kJ .
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