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Mandarinka [93]
3 years ago
8

This molecule can be synthesized from an alkyne anion and an alkyl bromide. However, there are two ways in which this molecule c

an be formed. One way uses a higher molecular weight alkyne anion (Part 1) and the other uses a lower molecular weight anion (Part 2). Draw the two versions in the boxes below. Omit spectator ions.

Chemistry
1 answer:
kozerog [31]3 years ago
4 0

Answer:

See figures

Explanation:

In this case, we will have different options around the<u> triple bond</u>. On part 1 we have to use the <u>bigger anion</u>, so we have to use the anion in which the <u>benzene ring is included </u>therefore the <u>ethyl</u> would be the <u>halide</u> (see figure 1).

On part 2 we have to use the <u>smaller anion</u>, so the <u>ethyl group</u> would be the anion and the other part of the molecule would be the <u>alkyl halide</u> (see figure 2).

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Calculate the Equilibrium constant Kc at 25 C from the free - energy change for the following reaction . Zn(s) + 2Ag+(aq)&lt;---
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Answer:  Kc=1.24*10^5^2

Explanation: For the given reaction:

Kc=\frac{[Zn^+^2]}{[Ag^+]^2}

Concentrations of the ions are not given so we need to think about another way to calculate Kc.

We can calculate the free energy change using the standard cell potential as:

\Delta G^0=-nFE^0_c_e_l_l

E^0_c_e_l_l can be calculated using standard reduction potentials.

Standard reduction potential for zinc is -0.76 V and for silver, it is +0.78 V.

E^0_c_e_l_l = E^0_c_a_t_h_o_d_e+E^0_a_n_o_d_e

Reduction takes place at anode and oxidation at cathode. As silver is reduced, it is cathode. Zinc is oxidized and so it is anode.

E^0_c_e_l_l  = 0.78 V - (-0.76 V)

E^0_c_e_l_l  = 0.78 V + 0.76 V

E^0_c_e_l_l  = 1.54 V

Value of n is two as two moles of electrons are transferred in the cell reaction F is Faraday constant and its value is 96485 C/mol of electron .

\Delta G^0=-(2*96485*1.54)

\Delta G^0 = -297173.8 J

Now we can calculate Kc using the formula:

\Delta G^0=-RTlnKc

T = 25+273 = 298 K

R = 8.314JK^-^1mol^-^1

--297173.8 = -(8.314*298)lnKc

297173.8 = 2477.572*lnKc

lnKc=\frac{297173.8}{2477.572}

lnKc = 119.946

Kc=e^1^1^9^.^9^4^6

Kc=1.24*10^5^2

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