What does refractometer measure?
2 answers:
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The mentioned molecule with formula, CH₃NO where no bond is found between N and O can be depicted as formamide is shown in the attachment below.
The formal charges = Number of valence electrons for the atom (V) - the number of electrons in lone pairs (N) - 1/2 (number of electrons in bond pairs, B)
FC = V - N - B/2
Thus, there is a need to calculate valence electrons, electrons in lone pairs, and the number of electrons in bond pairs for each atom in the mentioned molecule.
V or valence electrons on C = 4e, on H = 1e, on N = 5e, and on O = 6e.
N or electrons in lone pairs on C = 0e, on H = 0e, on N = 2e, and on O = 4e.
B or number of electrons in bond pairs for C = 8e, for H = 2e, for N = 6e, and for O = 4e.
Thus, the formal charges for each will be,
C = 4 - 0 - (8/2) = 0
H = 1 - 0 - (2/2) = 0
N = 5 - 2 - (6/2) = 0
O = 6 - 4 - (4/2) = 0
Lewis dot structure for the given molecule is given in the attachment below:
Answer:
Explanation:
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In this case, since the equation we use to model the heat exchange into the calorimeter and compute the heat of reaction is:
We plug in the mass of water, temperature change and specific heat to obtain:
Now, this enthalpy of reaction corresponds to the combustion of propyne:
Whose enthalpy change involves the enthalpies of formation of propyne, carbon dioxide and water, considering that of propyne is the target:
However, the enthalpy of reaction should be expressed in kJ per moles of C3H4, so we divide by the appropriate moles in 7.00 g of this compound:
Now, we solve for the enthalpy of formation of C3H4 as shown below:
So we plug in to obtain (enthalpies of formation of CO2 and H2O are found on NIST data base):
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