Why does a reaction slow down with time?
2 answers:
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<u>Answer:</u> The of the reaction at given temperature is -12.964 kJ/mol.
<u>Explanation:</u>
For the given chemical reaction:
The expression of for the given reaction:
We are given:
Putting values in above equation, we get:
To calculate the Gibbs free energy of the reaction, we use the equation:
where,
= Gibbs' free energy of the reaction = ?
= Standard gibbs' free energy change of the reaction = 0 J (at equilibrium)
R = Gas constant =
T = Temperature =
= equilibrium constant in terms of partial pressure =
Putting values in above equation, we get:
Hence, the of the reaction at given temperature is -12.964 kJ/mol.
<h3>Answer:</h3>
The Alkane formed is 5,5-dibromo-2,2,3-trimethylhexane. as shown below in attached scheme (Green Color).
<h3>Explanation:</h3>Alkynes like Alkenes undergo <em>Electrophillic Addition Reactions</em>. The reaction given is a two step reaction. In step 1, the Alkyne adds first equivalent of HBr obeying <em>Markovnikov's rule</em> (i.e. Bromine will add to carbon containing less number of hydrogen atoms) and forms <em>2-bromo-4,5,5-trimethylhex-1-ene</em>. In step 2, the alkene formed in first step (2-bromo-4,5,5-trimethylhex-1-ene) undergoes addition reaction with the second equivalent of HBr via Markovnikov's rule to produce <em>5,5-dibromo-2,2,3-trimethylhexane</em>.
The scheme is attached below, Blue color is assigned to starting Alkyne, Red color is assigned to intermediate Alkene and Green color is assigned to product Alkane respectively.