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Korolek [52]
3 years ago
6

Draw the product that is expected when hexanoyl chloride is treated with Et2CuLi

Chemistry
1 answer:
PolarNik [594]3 years ago
4 0

Answer:

Product formed is octan-3-one.

Explanation:

Et_2CuLi is a Gilman reagent. General formula of Gilman reagent is R_2CuLi.

Where R is alkyl group or aryl group.

Gilman reagents react with the organo halides to replace halides with alkyl group or aryl group and this reaction is known as Corey–House synthesis.

When hexanoyl chloride is treated with Et_2CuLi, the chloride group of the hexanoyl chloride is substituted with the ethyl group of the Et_2CuLi to form octan-3-one with the removal of EtCu and LiCl.

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Compare Boyle's law, Charles's law, and Avogadro's law. a. What remains constant in each law? b. What are the variables in each
zavuch27 [327]

Answer:

a)

In Boyle's Law, the variable that remains constant is the absolute temperature of the gas.

In Charle's Law, the variable that remains constant is the pressure of the gas.

In Avogadro's Law, the variables that remain constant are pressure and temperature of the gas.

b)

In Boyle's Law, the variables involved are pressure and volume: the law states that for a fixed mass of ideal gas at constant temperature, the pressure of the gas is inversely proportional to the volume:

p\propto \frac{1}{V}

where p is the pressure of the gas and V the volume.

In Charle's Law, the variables involved are volume and temperature: the law states that for a  fixed mass of ideal gas at constant pressure, the volume of the gas is directly proportional to the temperature:

V\propto T

where V is the volume of the gas and T the temperature.

In Avogadro's Law, the variables involved are the volume and the number of moles: the law states that for an ideal gas kept at constant pressure and temperature, the volume of the gas is directly proportional to the number of moles:

V\propto n

Where V is the volume of the gas and n the number of moles.

c)

See the graphs of the three Laws in attachment:

- First graph: Boyle's Law, which shows that the pressure of the gas is inversely proportional to the volume

- Second Graph: Charle's Law, which shows that the volume of the gas is directly proportional to the absolute temperature

- Third graph: Avogadro's Law, which shows that the volume of the gas is directly proportional to the number of moles of the gas

d)

Here we want to re-write the three laws by making V the subject.

For Boyle's law, we get:

V\propto \frac{1}{p}

For Charle's Law, we get:

V\propto T

For Avogadro's Law, we get:

V\propto n

Therefore, we see that the two laws that show a direct proportionality are Charle's Law and Avogadro's Law, while Boyle's Law shows an inverse proportionality between the two variables.

8 0
4 years ago
What is the fraction of the hydrogen atom's volume that is occupied by the nucleus? the bohr radius is 0.529×10−10m?
Arturiano [62]

Volume of a sphere = 4/3 x pi x r^3

When put a fraction of volume constant 4/3 x pi cancels out.

So only cube of radii remains.

Radius of proton = 10^-15 m (Fact; remember it)

Radius of total Hydrogen atom = 0.529 × 10^−10 m

Fraction of Volumes : R'^3/R^3 = (R/R)^3

Fraction = ((10^-15)/(0.529 × 10^−10m.))^3= (1/52900)^3 =

6.755 x 10^-15

6 0
3 years ago
Calculate the ionization energy of doubly ionized lithium, li2+, which has z=3.
GrogVix [38]
<span>Answer: I'm assuming the question is asking when it "jumps" from level 2 to level 1. In which case: 1/λ = Rh(1/nf^2 - 1/nfi^2) = 1.10x10^7 (1/1^2 - 1/2^2) = 1.10x10^7 ( 1 - 0.25) = 1.10 x10^7 (0.75) λ = 1.21 x 10^-7 m The wavelength produced will be about 1.21 x 10^ -7 m, or 121 nm.</span>
6 0
4 years ago
Can someone help with this pls!!
patriot [66]

Answer:

2

Explanation:

good vibes

8 0
3 years ago
Almost. treating an acyl chloride with a grignard reagent tends to form (via two steps) an alcohol. what reagent forms the keton
PIT_PIT [208]
Reaction of Acyl Halides with Grignard reagent results in the formation of Ketones in first step. While in second step reaction of Grignard reagent with Ketones results in the formation of Tertiary Alcohols.

If you want to stop the reaction at Ketone stage then you are required to use another mild reactive organometallic compound. In our case we will use Organocuprates. Organocuprates are also known as Gilman Reagents. These reagents does not add to ketones, aldehydes and esters but they can add to acid halides to produce Ketones.

8 0
3 years ago
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