Consider the reaction co(g)+nh3(g)âhconh2(g), kc=0.900 if a reaction vessel initially contains only co and nh3 at concentrations
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In reaction 1 of the Krebs cycle, acetyl‑CoA formed in the pyruvate dehydrogenase reaction condenses with the four‑carbon compound to form <em>citrate </em>with the elimination of coenzyme A. Since the product has three carboxyl groups, this pathway is referred to as the cycle. In reaction 2 of the Krebs cycle, this product then undergoes to form<em> isocitrate. </em>The enzyme is called aconitase because the compound cis‑aconitate is the <em>intermediate product</em> of the reaction. Reaction 3 eliminates CO2 to form the five‑carbon dicarboxylic acid <em>α-cetoglutarate. </em>Oxidation also occurs, with electrons transferred from the substrate to <em>COO-</em> . Consequently, this reaction is an oxidative decarboxylation.
In the image, you can see the reaction 2 in Krebs cycle is a two steps reaction with an intermediate cis-aconitase and a product called isocitrate.
Answer:
Explanation:
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In this case, it is widely known that for isochoric processes, the change in the enthalpy is computed by:
Whereas the change in the internal energy is computed by:
So we compute the initial and final temperatures for one mole of the ideal gas:
Next, the change in the internal energy, since the volume-constant specific heat could be assumed as ³/₂R:
Then, the volume-pressure product in Joules:
Finally, the change in the enthalpy for the process:
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