Answer:
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1) Answer is: c) The reaction will proceed right.
Balanced chemical reaction: N₂(g) + 3H₂(g) ⇄ 2NH₃(g) ΔH = +92 kJ.
Reducing the volume of the system increase the partial pressures of the products and reactants.
With a pressure increase due to a decrease in volume, the side of the equilibrium with fewer moles is more favorable, there are 4 moles at the left side (three moles of hydrogen and one mole of nitrogen) and 2 moles (ammonia) at the right side of the reaction.
2) Answer is: d) The partial pressure of ammonia will increase.
This reaction is endothermic (enthalpy is higher than zero), which means that heat is added.
According to Le Chatelier's principle when the reaction is endothermic heat is included as a reactant and when the temperature increased, the heat of the system increase, so the system consume some of that heat by shifting the equilibrium to the right, producing more ammonia.
Answer:
Final pH of the solution: 2.79.
Explanation:
What's in the solution after mixing?
,
where
is the concentration of the solute,
is the number of moles of the solute, and
is the volume of the solution.
.
Acetic (ethanoic) acid:
.
.
Hydrochloric acid HCl:
.
.
HCl is a strong acid. It will completely dissociate in water to produce H⁺. The H⁺ concentration in the solution before acetic acid dissociates shall also be
.
The Ka value of acetic acid is considerably small. Acetic acid is a weak acid and will dissociate only partially when dissolved. Construct a RICE table to predict the portion of acetic acid that will dissociate. Let the change in acetic acid concentration be
.
.
.
.
Rewrite as a quadratic equation and solve for
:

.
The pH of a solution depends on its H⁺ concentration.
At equilibrium
.
.
If the concentration of fluoride anion and aluminum cation was increased to 5M, then there would be decrease in Ecell by 0.055 volts
The standard reduction potential of Fluoride anion and aluminum cation are -
2Al -----> 2Al3+ + 6e-
cell = +1.66
6e- + 3F2 -----> 6F-
cell = +2.87
The complete reaction is -
2Al + 3F2 ------> 2Al3+ + 6F-
= +4.53
Using Nernst Equation :-
E =
– 0.0592/n*log[Al3+]^2[F-]^6
n = 6 (n = number of transferred electrons)
E = +4.53 - 0.0592/6*log(5)^2(5)^6
E = +4.53 - 0.00987*log(25)(1.56 x 10^4)
E = +4.53 – 0.00987*log(3.9 x 10^5)
E = + 4.53 -0.00987(5.59)
E = + 4.53 - 0.055
E = +4.47
The change in Ecell = 5 - 4.47 = 0.055V
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