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Delicious77 [7]
3 years ago
10

Select the answer which shows the correct order, slowest to fastest, of the relative rate of diffusion of the gases.

Chemistry
1 answer:
IrinaK [193]3 years ago
7 0

Diffusion is the process of a substance spreading out to evenly fill its container or environment. Rate of diffusion of a gas is inversely proportional to the molar mass of the gas.

Rate of diffusion \propto \frac{1}{Molar mass}

Lighter(lower) the molar mass of the gas , faster will be its rate of diffusion and heavier (higher) the molar mass of the gas , slower will be its rate of diffusion.

We have to arrange the given gases from slowest rate of diffusion to fastest rate of diffusion that means we need to arrange gases from higher molar mass to lower molar mass.

Molar mass of given gases are :

Cl = 35.5 g/mol

Xe = 131.29 g/mol

He = 4.00 g/mol

N = 14.00 g/mol

So correct order for slowest rate of diffusion (highest molar mass) to fastest rate of diffusion (lowest molar mass) is :

Xe , Cl , N , He

Xe having the highest molar mass will have the slowest rate of diffusion and He with lowest molar mass will have the fastest rate of diffusion, so option 'c' is correct.

Note : Slowest rate of diffusion = High Molar Mass

Fastest rate of diffusion = Low Molar Mass



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Calculate ΔrG∘ at 298 K for the following reactions.CO(g)+H2O(g)→H2(g)+CO2(g)2-Predict the effect on ΔrG∘ of lowering the temper
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Answer:

1) ΔG°r(298 K) = - 28.619 KJ/mol

2) ΔG°r will decrease with decreasing temperature

Explanation:

  • CO(g) + H2O(g) → H2(g) + CO2(g)

1) ΔG°r = ∑νiΔG°f,i

⇒ ΔG°r(298 K) = ΔG°CO2(g) + ΔG°H2(g) - ΔG°H2O(g) - ΔG°CO(g)

from literature, T = 298 K:

∴ ΔG°CO2(g) = - 394.359 KJ/mol

∴ ΔG°CO(g) = - 137.152 KJ/mol

∴ ΔG°H2(g) = 0 KJ/mol........pure substance

∴ ΔG°H2O(g) = - 228.588 KJ/mol

⇒ ΔG°r(298 K) = - 394.359 KJ/mol + 0 KJ/mol - ( - 228.588 KJ/mol ) - ( - 137.152 KJ7mol )

⇒ ΔG°r(298 K) = - 28.619 KJ/mol

2) K = e∧(-ΔG°/RT)

∴ R = 8.314 E-3 KJ/K.mol

∴ T = 298 K

⇒ K = e∧(-28.619/(8.314 E-3)(298) = 9.624 E-6

⇒ ΔG°r = - RTLnK

If T (↓) ⇒ ΔG°r (↓)

assuming T = 200 K

⇒ ΔG°r(200 K) = - (8.314 E-3)(200)Ln(9.624E-3)

⇒ ΔG°r (200K) = - 19.207 KJ/mol < ΔG°r(298 K) = - 28.619 KJ/mol

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