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professor190 [17]
3 years ago
5

Write the mechanism for the acid catalyzed hydrolysis of methyl benzoate

Chemistry
1 answer:
Elis [28]3 years ago
7 0
Hydrolysis of Methyl Benzoate yields Benzoic Acid and Methanol. This reaction is also called as Tranesterification (reverse of esterification). Acid in this reaction protonates the carbonyl oxygen, resulting in increasing electrophillic character of carbonyl carbon. Water acts as a nucleophile and methoxide leaves as a good leaving group. Mechanism is shown below,

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Calculate the hydronium ion concentration in an aqueous solution with a poh of 4.33 at 25°c.
Jlenok [28]

Taking into account the definition of pH and pOH, the hydronium ion concentration in an aqueous solution with a pOH of 4.33 at 25°c is 2.138×10⁻¹⁰ M.

<h3>Definition of pH</h3>

pH is a measure of acidity or alkalinity that indicates the amount of hydrogen ions present in a solution or substance.

The pH is defined as the negative base 10 logarithm of the activity of hydrogen ions, that is, the concentration of hydrogen ions or  hydronium ion H₃O⁺:

pH= - log [H⁺]= - log [H₃O⁺]

<h3>Definition of pOH</h3>

Similarly, pOH is a measure of hydroxyl ions in a solution and is expressed as the logarithm of the concentration of OH⁻ ions, with the sign changed:

pOH= - log [OH⁻]

<h3>Relationship between pH and pOH</h3>

The following relationship can be established between pH and pOH:

pOH + pH= 14

<h3>Concentration of hydronium ions</h3>

Being pOH= 4.33, pH is calculated as:

pH + 4.33= 14

pH= 14 - 4.33

<u><em>pH= 9.67</em></u>

Replacing in the definition of pH the concentration of hydronium ions is obtained:

- log [H₃O⁺]= 9.67

Solving:

[H₃O⁺]= 10⁻⁹ ⁶⁷

<u><em>[H₃O⁺]= 2.138×10⁻¹⁰ M</em></u>

Finally, the hydronium ion concentration in an aqueous solution with a pOH of 4.33 at 25°c is 2.138×10⁻¹⁰ M.

Learn more about pH and pOH:

brainly.com/question/16032912

brainly.com/question/13557815

#SPJ1

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2 years ago
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