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labwork [276]
3 years ago
10

As a chemical reaction proceeds toward equilibrium, the free energy of the system decreases at constant temperature and constant

pressure. true or fals
Chemistry
1 answer:
olganol [36]3 years ago
8 0

Answer:

True

Explanation:

GIBBS FREE ENERGY (G) Gibbs free energy is a thermodynamic function It is a state function. G = H - TS At constant temperature At constant pressure and temperature An increase in S corresponds to a decrease in free energy

Constant free energy (G) P, T The important thing about free energy is that whenever the pressure and temperature are constant, we can determine the spontaneity of a process only in terms of the thermodynamic properties of the system G = H - TS The Free energy change is a measure of the change in the total entropy of a system and its environment at constant temperature and pressure. <u>Spontaneous processes at constant temperature and pressure are accompanied by a decrease in free energy</u>.

At constant temperature and pressure, the direction of spontaneous change is towards the lowest free energy. <u>The equilibrium state of a system corresponds to the lowest point of the free energy curve </u>.

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Solid ammonium chloride, NH4Cl, is formed by the reaction of gaseous ammonia, NH3, and hydrogen chloride, HCl. NH3(g)+HCl(g)⟶NH4
Mashutka [201]

9.41 atm is the pressure in atmospheres of the gas remaining in the flask

<h3>What is the pressure in atmospheres?</h3>

The equation NH3(g) + HCl(g) ==> NH4Cl(s) is balanced.

Divide the moles of each reactant by its coefficient in the balanced equation, and the limiting reagent is identified as the one whose value is less. With the issue we now have...

6.44 g NH3 times 1 mol NH3/17 g equals 0.3688 moles of NH3 ( 1 = 0.3688)

HCl: 6.44 g of HCl times one mole of HCl every 36.5 g equals 0.1764 moles ( 1 = 0.1764). CONTROLLING REAGENT

NH4Cl will this reaction produce in grams

0.1764 moles of HCl multiplied by one mole of NH4Cl per mole of HCl results in 9.44 g of NH4Cl (3 sig. figs.)

the gas pressure, measured in atmospheres, that is still in the flask

NH3(g) plus HCl(g) results in NH4Cl (s)

0.3688......0.1764............0..........

Initial

-0.1764....-0.1764........+0.1764...Change

Equilibrium: 0.1924.......0...............+0.1924

There are 0.1924 moles of NH3 and no other gases in the flask. This is at a temperature of 25 °C (+273 = 298 °K) in a volume of 0.5 L. After that, we may determine the pressure by using the ideal gas law (P).

PV = nRT

P = nRT/V = 0.1924 mol, 0.0821 latm/mol, and 298 Kmol / 0.5 L

P = 9.41 atm

9.41 atm is the pressure in atmospheres of the gas remaining in the flask

To learn more about balanced equation refer to:

brainly.com/question/11904811

#SPJ1

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