Answer:
Explanation:
It is volume-volume problems that does not require the use of molar mass.
Answer:
Explanation:
Given that:
the temperature
= 250 °C= ( 250+ 273.15 ) K = 523.15 K
Pressure = 1800 kPa
a)
The truncated viral equation is expressed as:

where; B = -
C = -5800 
R = 8.314 × 10³ cm³ kPa. K⁻¹.mol⁻¹
Plugging all our values; we have


Multiplying through with V² ; we have


V = 2250.06 cm³ mol⁻¹
Z = 
Z = 
Z = 0.931
b) The truncated virial equation [Eq. (3.36)], with a value of B from the generalized Pitzer correlation [Eqs. (3.58)–(3.62)].
The generalized Pitzer correlation is :












The compressibility is calculated as:


Z = 0.9386


V = 2268.01 cm³ mol⁻¹
c) From the steam tables (App. E).
At 
V = 0.1249 m³/ kg
M (molecular weight) = 18.015 gm/mol
V = 0.1249 × 10³ × 18.015
V = 2250.07 cm³/mol⁻¹
R = 729.77 J/kg.K
Z = 
Z = 
Z = 0.588
Answer:
pH = 12.33
Explanation:
Lets call HA = butanoic acid and A⁻ butanoic acid and its conjugate base butanoate respectively.
The titration reaction is
HA + KOH ---------------------------- A⁻ + H₂O + K⁺
number of moles of HA : 118.3 ml/1000ml/L x 0.3500 mol/L = 0.041 mol HA
number of moles of OH : 115.4 mL/1000ml/L x 0.400 mol/L = 0.046 mol A⁻
therefore the weak acid will be completely consumed and what we have is the unreacted strong base KOH which will drive the pH of the solution since the contribution of the conjugate base is negligible.
n unreacted KOH = 0.046 - 0.041 = 0.005 mol KOH
pOH = - log (KOH)
M KOH = 0.005 mol / (0.118.3 +0.1154)L = 0.0021 M
pOH = - log (0.0021) = 1.66
pH = 14 - 1.96 = 12.33
Note: It is a mistake to ask for the pH of the <u>acid solutio</u>n since as the above calculation shows we have a basic solution the moment all the acid has been consumed.
Answer:
a. Oxygen gas is limiting
Explanation:
hydrogen gas and oxygen gas are reacted to form water
2H₂ + O₂ → 2H₂O
the above balanced equation shows that 2 moles of H₂ is required for 1 mole of O₂
Given equal masses of H₂ and O₂
assuming 'x' gm for each, no. of moles of each gas =
no. of moles of H₂ = x/2 = 0.5x moles
no.of moles of O₂ = x/32 = 0.031x moles
This shows that no. of moles of O₂ is very less so O₂ will become the limiting reagent.