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timama [110]
3 years ago
7

Suppose 10 mg of deprenyl is diluted in 10 mL of water. What is the a) mass fraction and b) mol fraction of deprenyl in the solu

tion?
Chemistry
1 answer:
motikmotik3 years ago
4 0

Answer:

(a) Mass fraction of deprenyl in the solution is 0.55

(b) Mole fraction of deprenyl in the solution is0.11

Explanation:

(a) Mass of deprenyl = 10mg = 10/1000 = 0.01g

Volume of water = 10mL = 10/1000 = 0.01L

1 mole of a substance contains 22.4L of the substance

0.01L of water = 0.01/22.4 = 0.00045mole of water

MW of water = 18g/mole

Mass of water = 0.00045mole × 18g/mole = 0.0081g

Mass of solution = mass of deprenyl + mass of water = 0.01g + 0.0081g = 0.0181g

Mass fraction of deprenyl = mass of deprenyl/mass of solution = 0.01g/0.0181g = 0.55

(b) Molecular weight (MW) of deprenyl (C13H17N) = 187g/mole

Number of moles of deprenyl = mass/MW = 0.01/187 = 0.000053mole

Total moles of solution = moles of deprenyl + moles of water = 0.0000053mole + 0.00045mole = 0.000503mole

Mole fraction of deprenyl in the solution = moles of deprenyl/moles of solution = 0.000053mole/0.000503mole = 0.11

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4 years ago
Consider the following reaction: CO(g)+2H2(g)⇌CH3OH(g) Kp=2.26×104 at 25 ∘C. Calculate ΔGrxn for the reaction at 25 ∘C under eac
valentinak56 [21]

Answer : The value of \Delta G_{rxn} is, 8.867kJ/mole

Explanation :

The formula used for \Delta G_{rxn} is:

\Delta G_{rxn}=\Delta G^o+RT\ln Q   ............(1)

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\Delta G_^o =  standard Gibbs free energy

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First we have to calculate the \Delta G_^o.

Formula used :

\Delta G^o=-RT\times \ln K_p

Now put all the given values in this formula, we get:

\Delta G^o=-(8.314J/mole.K)\times (298K)\times \ln (2.26\times 10^{4})

\Delta G^o=-24839.406J/mole=-24.83\times 10^3J/mole=-24.83kJ/mole

Now we have to calculate the value of 'Q'.

The given balanced chemical reaction is,

CO(g)+2H_2(g)\rightarrow CH_3OH(g)

The expression for reaction quotient will be :

Q=\frac{(p_{CH_3OH})}{(p_{CO})\times (p_{H_2})^2}

In this expression, only gaseous or aqueous states are includes and pure liquid or solid states are omitted.

Now put all the given values in this expression, we get

Q=\frac{(1.4)}{(1.2\times 10^{-2})\times (1.2\times 10^{-2})^2}

Q=8.1\times 10^{5}

Now we have to calculate the value of \Delta G_{rxn} by using relation (1).

\Delta G_{rxn}=\Delta G^o+RT\ln Q

Now put all the given values in this formula, we get:

\Delta G_{rxn}=-24.83kJ/mole+(8.314\times 10^{-3}kJ/mole.K)\times (298K)\ln (8.1\times 10^{5})

\Delta G_{rxn}=8.867\times 10^3J/mole=8.867kJ/mole

Therefore, the value of \Delta G_{rxn} is, 8.867kJ/mole

3 0
3 years ago
If the change in entropy of the surroundings for a process at 451 k and constant pressure is -326 j/k, what is the heat flow abs
Arisa [49]

If the change in entropy of the surroundings for a process at 451 k and constant pressure is -326 j/k, then heat flow absorbed (in kj) by the system is -147.026kJ.

<h3>What is entropy? </h3>

The entropy of particle is defined as how random it move. It shows the randomness of the system or may be disorders of the system. It is used to measure the unavailable energy for performing useful work.

Unit of entropy = J/K

<h3>Formula:</h3>

∆s = ∆Q/T

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∆Q = 147.026 kJ

Thus we find that the heat absorbed by the system is 147.026 kJ.

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