Answer:
35Cl = 75.9 %
37Cl = 24.1 %
Explanation:
Step 1: Data given
The relative atomic mass of Chlorine = 35.45 amu
Mass of the isotopes:
35Cl = 34.96885269 amu
37Cl = 36.96590258 amu
Step 2: Calculate percentage abundance
35.45 = x*34.96885269 + y*36.96590258
x+y = 1 x = 1-y
35.45 = (1-y)*34.96885269 + y*36.96590258
35.45 = 34.96885269 - 34.96885269y +36.96590258y
0.48114731 = 1,99704989y
y = 0.241 = 24.1 %
35Cl = 34.96885269 amu = 75.9 %
37Cl = 36.96590258 amu = 24.1 %
Our reaction balanced equation at equilibrium N2(g) + 3 H2(g) ↔ 2 NH3(g)
and we have the Kp value at equilibrium = 4.51 X 10^-5
A) 98 atm NH3, 45 atm N2, 55 atm H2
when Kp = [P(NH3)]^2 / [P(N2)] * [P(H2)]^3
= 98^2 / (45 * 55^3) = 1.28 x 10^-3
by comparing the Kp by the Kp at equilibrium(the given value) So,
Kp > Kp equ So the mixture is not equilibrium,
it will shift leftward (to decrease its value) towards the reactants to achieve equilibrium.
B) 57 atm NH3, 143 atm N2, no H2
∴ Kp = [P(NH3)]^2 / [P(N2)]
= 57^2 / 143 = 22.7
∴Kp> Kp equ (the given value)
∴it will shift leftward (to decrease its value) towards reactants to achieve equilibrium.
c) 13 atm NH3, 27 atm N2, 82 atm H2
∴Kp = [P(NH3)]^2 / [P(N2)] * [P(H2)]^3
= 13^2 / (27* 82^3) = 1.14 X 10^-5
∴ Kp< Kp equ (the given value)
∴it will shift rightward (to increase its value) towards porducts to achieve equilibrium.