A solution (in this experiment solution of NaNO₃) freezes at a lower temperature than does the pure solvent (deionized water). The higher the
solute concentration (sodium nitrate), freezing point depression of the solution will be greater.
Equation describing the change in freezing point:
ΔT = Kf · b · i.
ΔT - temperature change from pure solvent to solution.
Kf - the molal freezing point depression constant.
b - molality (moles of solute per kilogram of solvent).
i - Van’t Hoff Factor.
First measure freezing point of pure solvent (deionized water). Than make solutions of NaNO₃ with different molality and measure separately their freezing points. Use equation to calculate Kf.
Answer:

Explanation:
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In this case, for a concentration of 0.42 M of benzoic acid whose Ka is 6.3x10⁻⁵ in 0.33 M sodium benzoate, we use the Henderson-Hasselbach equation to compute the required pH:
![pH=pKa+log(\frac{[base]}{[acid]} )](https://tex.z-dn.net/?f=pH%3DpKa%2Blog%28%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D%20%29)
Whereas the concentration of the base is 0.33 M and the concentration of the acid is 0.42 M, thereby, we obtain:
![pH=-log(Ka)+log(\frac{[base]}{[acid]} )\\\\pH=-log(6.3x10^{-5})+log(\frac{0.33M}{0.42M} )\\\\pH=4.1](https://tex.z-dn.net/?f=pH%3D-log%28Ka%29%2Blog%28%5Cfrac%7B%5Bbase%5D%7D%7B%5Bacid%5D%7D%20%29%5C%5C%5C%5CpH%3D-log%286.3x10%5E%7B-5%7D%29%2Blog%28%5Cfrac%7B0.33M%7D%7B0.42M%7D%20%29%5C%5C%5C%5CpH%3D4.1)
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Partial pressure of gas A is 1.31 atm and that of gas B is 0.44 atm.
The partial pressure of a gas in a mixture can be calculated as
Pi = Xi x P
Where Pi is the partial pressure; Xi is mole fraction and P is the total pressure of the mixture.
Therefore we have Pa = Xa x P and Pb = Xb x P
Let us find Xa and Xb
Χa = mol a/ total moles = 2.50/(2.50+0.85) = 2.50/3.35 = 0.746
Xb = mol b/total moles = 0.85/(2.50+0.85) = 0.85/3.35 = 0.254
Total pressure P is given as 1.75 atm
Pa = Xa x P = 0.746 x 1.75 = 1.31atm
Partial pressure of gas A is 1.31 atm
Pb = Xb x P = 0.254 x 1.75 = 0.44atm
Partial pressure of gas B is 0.44 atm.
Learn more about Partial pressure here:
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Answer: To solve this question, we need to use the Avogadro's Number, which is a constant first discovered by Amadeo Avogadro, an Italian scientist. He discovered that in a mole of a substance, there are 6,02*10²³ molecules. Using this relationship, we apply the following conversion factor:
So, 8,50 * 10²⁴ molecules of Na₂SO₃ represent 14,12 moles of Na₂SO₃
Explanation: