Answer:
Limestone caves are formed when acid rain occurs.
Explanation:
When chalk pieces which is made of calcium carbonate react with acetic acid, it produces carbon dioxide, calcium acetate, and water. When calcium carbonate react with Carbonated Water produces calcium bicarbonate. Limestone cave forms when the dissolution of limestone occur when rainwater which is acidic due to the addition of carbondioxide in the air react with limestone. This dissolution removes the lime from the rock and caves are formed.
Answer:
The enthalpy of the reaction is coming out to be -380.16 kJ.
Explanation:
Enthalpy change is defined as the difference in enthalpies of all the product and the reactants each multiplied with their respective number of moles. It is represented as 
The equation used to calculate enthalpy change is of a reaction is:
![\Delta H_{rxn}=\sum [n\times \Delta H_f(product)]-\sum [n\times \Delta H_f(reactant)]](https://tex.z-dn.net/?f=%5CDelta%20H_%7Brxn%7D%3D%5Csum%20%5Bn%5Ctimes%20%5CDelta%20H_f%28product%29%5D-%5Csum%20%5Bn%5Ctimes%20%5CDelta%20H_f%28reactant%29%5D)
For the given chemical reaction:
The equation for the enthalpy change of the above reaction is:
![\Delta H_{rxn}=[(2 mol\times \Delta H_f_{(N_2O)})+(2 mol\times\Delta H_f_{(H_2O)} )]-[(1 mol\times \Delta H_f_{(N_2H_4)})+(1 mol\times \Delta H_f_{(N_2O_4)})]](https://tex.z-dn.net/?f=%5CDelta%20H_%7Brxn%7D%3D%5B%282%20mol%5Ctimes%20%5CDelta%20H_f_%7B%28N_2O%29%7D%29%2B%282%20mol%5Ctimes%5CDelta%20H_f_%7B%28H_2O%29%7D%20%29%5D-%5B%281%20mol%5Ctimes%20%5CDelta%20H_f_%7B%28N_2H_4%29%7D%29%2B%281%20mol%5Ctimes%20%5CDelta%20H_f_%7B%28N_2O_4%29%7D%29%5D)
We are given:
Putting values in above equation, we get:
![\Delta H_{rxn}=[(2 mol\times 81.6 kJ/mol)+2 mol\times -241.8 kJ/mol)]-[(1 mol\times (50.6 kJ/mol))+(1 mol\times (9.16))]\\\\\Delta H_{rxn}=-380.16 kJ](https://tex.z-dn.net/?f=%5CDelta%20H_%7Brxn%7D%3D%5B%282%20mol%5Ctimes%2081.6%20kJ%2Fmol%29%2B2%20mol%5Ctimes%20-241.8%20kJ%2Fmol%29%5D-%5B%281%20mol%5Ctimes%20%2850.6%20kJ%2Fmol%29%29%2B%281%20mol%5Ctimes%20%289.16%29%29%5D%5C%5C%5C%5C%5CDelta%20H_%7Brxn%7D%3D-380.16%20kJ)
Hence, the enthalpy of the reaction is coming out to be -380.16 kJ.
Answer:
[OH⁻] = 4.3 x 10⁻¹¹M in OH⁻ ions.
Explanation:
Assuming the source of the carbonate ion is from a Group IA carbonate salt (e.g.; Na₂CO₃), then 0.115M Na₂CO₃(aq) => 2(0.115)M Na⁺(aq) + 0.115M CO₃²⁻(aq). The 0.115M CO₃²⁻ then reacts with water to give 0.115M carbonic acid; H₂CO₃(aq) in equilibrium with H⁺(aq) and HCO₃⁻(aq) as the 1st ionization step.
Analysis:
H₂CO₃(aq) ⇄ H⁺(aq) + HCO₃⁻(aq); Ka(1) = 4.3 x 10⁻⁷
C(i) 0.115M 0 0
ΔC -x +x +x
C(eq) 0.115M - x x x
≅ 0.115M
Ka(1) = [H⁺(aq)][HCO₃⁻(aq)]/[H₂CO₃(aq)] = [(x)(x)/(0.115)]M = [x²/0.115]M
= 4.3 x 10⁻⁷ => x = [H⁺(aq)]₁ = SqrRt(4.3 x 10⁻⁷ · 0.115)M = 2.32 x 10⁻⁴M in H⁺ ions.
In general, it is assumed that all of the hydronium ion comes from the 1st ionization step as adding 10⁻¹¹ to 10⁻⁷ would be an insignificant change in H⁺ ion concentration. Therefore, using 2.32 x 10⁻⁴M in H⁺ ion concentration, the hydroxide ion concentration is then calculated from
[H⁺][OH⁻] = Kw => [OH⁻] = (1 x 10⁻¹⁴/2.32 x 10⁻⁴)M = 4.3 x 10⁻¹¹M in OH⁻ ions.
________________________________________________________
NOTE: The 2.32 x 10⁻⁴M value for [H⁺] is reasonable for carbonic acid solution with pH ≅ 3.5 - 4.0.
Answer:
water is H2O having different structure than alcohol R-OH which means they have different properties too.
Explanation:
In water one oxygen atom is covalently bound with two hydrogen atoms while alcohol is an organic compound having Oh group attached to the carbon chain.
Other than liquid water can occur in solid form that is ice and in gaseous form that is vapors too while alcohol only present in liquid form.
heat of evaporation of alcohol is lower than water means water need more heat to evaporate than alcohol that is why we can say alcohol having more cooling effect than water.
