Answer: The answer to the first one is the second option and the answer for the second one is the first option.
Explanation:
64158 calories is required
the answer is true the first one
1 mole of N2 produces 2 moles of NH3
OR...
14 x 2 grams of N2 produces 2(14 +3) grams of NH3
1 gram of N2 produces 34/28 grams of NH3
therefore, 56 grams produce (34/28 )x 56 =68 grams of NH3
the answer thus would be 68 grams of NH3