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levacccp [35]
3 years ago
5

Select the correct answer.

Chemistry
1 answer:
Sladkaya [172]3 years ago
5 0

Answer:

  • <u><em>Option D. There will be a shift toward the reactants.</em></u>

Explanation:

The reaction is:

       PCl_5(g)+heat\rightleftharpoons PCl_3(g)+Cl_2(g)

The application of LeChatelier's principle leads to consider the <em>heat</em> as a <em>reactant</em> or a product depending on if it is on the left side or the right side.

In this reaction, the <em>heat</em> is on the left side, thus it must be considered a <em>reactant</em>.

Decreasing the temperature is equivalent to remove or consume heat. Thus, the reaction must shif to the left to compensate that reduction of heat. That is the reverse reaction shall be favored.

In conclusion, <em>there will be a shift toward the reactants.</em>

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 Answer 2:
Hexane has a molecular formula of C6H14. It exhibits following structural isomers
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Answer 3: 
</span><span>Butane has two possible isomers but that decane has 75 possible isomers. This can be attributed to the fact that butane has 4 carbon atoms, while decane has 10 carbon atom. As the number of carbon atom increases, there are higher possible sites of linkage, in different fashion. Therefore, as number 69 of carbon atoms increases, number of different possible isomers increases. 

Answer 4:
It has been observed that, though isomers have same molecular formula, but the have different boiling points. Infact, branched isomers have lower boiling point as compared to linear isomers. For example, hexane has boiling point = 69 oC, 2 methyl pentane has boiling point = 60 oC, 2,4, dimethyl butane has boiling point = 58 oC and 2,2 dimethyl butane has boiling point = 50 oC. Thus, it can be observed that branched isomers have lower boiling points as compared to linear isomers. This can be attributed to lower van der Waal's forces of interaction in branched isomers as compared to linear isomers. 
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