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Chemistry

2 answers:

iogann1982 [59]2 years ago

8 0

2. is point source

3. is non point source

storchak [24]2 years ago

4 0

QUESTION 2: POINT SOURCE
QUESTION 3:NONE POINT SOURCE

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A voltaic cell consists of a Pb/Pb2+ half-cell and a Cu/Cu2+ half-cell at 25 ?C. The initial concentrations of Pb2+ and Cu2+ are

VARVARA [1.3K]

Answer:

a) Ecell = 0.5123 V

b) Ecell = 0.4695 V

c) [Pb2 +] = 4.75 M

Explanation:

The reaction at the cathode is represented as follows:

Cu2 + + 2e- -> Cu (s) Eocathode = 0.34 V

The reaction at the anode is equal to:

Pb (s) -> Pb2 + + 2e- Eoanode = -0.13 V

The number of moles of the electrons that are involved is equal to n = 2

Standard cell potential equals Eo = Eocathode - Eoanode = 0.34 V- (-0.13 V) = 0.47 V

The initial cell potential can be calculated with the following formula:

Ecell = Eocell - - 0.0592 / n) log ([(Pb2 +)] / [(Cu2 +)]) = 0.47 - (0.0592 / 2) log (0.052 / 1.4) = 0.5123 V

The reaction in the cell is equal to:

Cu2 + + Pb (s) -> Cu (s) + Pb2 +

The concentration of Cu2 that gives the exercise is equal 0.2 M

Therefore, the change in concentration for Cu2 + is equal to:

Cu2 + = 1.4 M - 0.2 M = 1.2 M

We use the formula from part a)

Ecell = Eocell - (0.0592 / n) log ([(Pb2 +)] / [(Cu2 +)]) = 0.47 - (0.0592 / 2) log (1,252 / 1.2) = 0.4695 V

To find the concentration of Pb2 + when there is a potential change in the cell of 0.37 V, we must clear the concentration of Pb2 + from the following formula:

Eccell = Echocell - (0.0592 / n) log (([Pb2 +]) / ([Cu2 +]))

0.0296 log ([Pb2 +] / [Cu2 +]) = (Eocélula - Ecélula / 0.0296)

Clearing Pb2 +:

[Pb2 +] = 4.75 M

8 0

3 years ago

Be sure to answer all parts. Nitric oxide, NO·, is a radical thought to cause ozone destruction by a mechanism similar to that o

SIZIF [17.4K]

Answer:

See image attached and explanation

Explanation:

The stratospheric ozone layer is very important in absorbing high-energy ultraviolet radiation that is harmful to living systems on earth. The concentration of ozone in the stratosphere is determined by both thermal and photochemical pathways for its decomposition. Nitric oxide, NO, is a trace constituent in the stratosphere that reacts with ozone to form nitrogen dioxide, NO2, and the diatomic oxygen molecule. The nitrogen-oxygen bond in NO2 is relatively weak. When an NO2 molecule encounters an oxygen atom, it transfers an oxygen, forming O2 and NO. The chemical reactions involved are formations of NO2 following by reaction of NO2 with atomic oxygen for form NO and O2. The sum of both reactions show that the overall reaction is simply the reaction of ozone with atomic oxygen to form two molecules of molecular oxygen. Hence, NO only serves as a catalyst, it does not undergo a permanent change itself.