Answer:
v = 2,66x10⁻⁵ P[H₂C₂O₄]
Explanation:
For the reaction:
H₂C₂O₄(g) → CO₂(g) + HCOOH(g)
At t = 0, the initial pressure is just of H₂C₂O₄(g). At t= 20000 s, pressures will be:
H₂C₂O₄(g) = P₀ - x
CO₂(g) = x
HCOOH(g) = x
P at t=20000 is:
P₀ - x + x + x = P₀+x. That means P at t=20000s - P₀ = x
For 1st point:
x = 92,8-65,8 = 27
Pressure of H₂C₂O₄(g) at t=20000s: 65,8-27 = 38,8
2nd point:
x = 130-92,1 = 37,9
H₂C₂O₄(g): 92,1 - 37,9 = 54,2
3rd point:
x = 157-111 = 46
H₂C₂O₄(g): 111-46 = 65
Now, as the rate law is :
v = k P[H₂C₂O₄]
Based on integrated rate law, k is:
(- ln P[H₂C₂O₄] + ln P[H₂C₂O₄]₀) / t = k
1st point:
k = 2,64x10⁻⁵
2nd point:
k = 2,65x10⁻⁵
3rd point:
k = 2,68x10⁻⁵
The averrage of this values is:
k = 2,66x10⁻⁵
That means law is:
v = 2,66x10⁻⁵ P[H₂C₂O₄]
I hope it helps!
The lewis structure is helpful in showing how the bonding between atoms of a molecule are. The lewis structure of ammonia would be that the nitrogen atom will share three pairs of electron with the three hydrogen atoms leaving nitrogen to have 1 lone pair.<span />
To solve this problem,
we can use the Henderson-Hasselbalch Equation which relates the pH to the measure
of acidity pKa. The equation is given as:<span>
<span>pH = pKa + log ([base]/[acid]) ---> 1</span></span>
Where,
[base] = concentration
of C2H3O2
in molarity or moles
<span>[acid] = concentration of HC2H3O2 in molarity or moles</span>
For the sake of easy calculation, let us assume that:
[base] = 1
[acid] = x
<span>
Therefore using equation 1,
4.24 = 4.74 + log (1 / x)
<span>log (1 / x) = - 0.5
1 / x = 0.6065 </span></span>
x =
1.65<span>
The required ratio of C2H3O2 /HC2H3O2 <span>
is 1:1.65 or 3:5. </span></span>
Erosion? As time passes, the continents move? Some crumble? I don't know but I tried