A. Real gases may be expected to deviate from Charles's law at high pressures.
C. Real gases may be expected to deviate from Charles's law near the liquefaction temperature.
Phosphorus tribromide is a covalent compound because they share electron pairs.
Missing in your question :
Ksp of(CaCO3)= 4.5 x 10 -9
Ka1 for (H2CO3) = 4.7 x 10^-7
Ka2 for (H2CO3) = 5.6 x 10 ^-11
1) equation 1 for Ksp = 4.5 x 10^-9
CaCO3(s)→ Ca +2(aq) + CO3-2(aq)
2) equation 2 for Ka1 = 4.7 x 10^-7
H2CO3 + H2O → HCO3- + H3O+
3) equation 3 for Ka2 = 5.6 x 10^-11
HCO3-(aq) + H2O(l) → CO3-2 (aq) + H3O+(aq)
so, form equation 1& 2&3 we can get the overall equation:
CaCO3(s) + H+(aq) → Ca2+(aq) + HCO3-(aq)
note: you could get the overall equation by adding equation 1 to the inverse of equation 3 as the following:
when the inverse of equation 3 is :
CO3-2 (aq) + H3O+ (aq) ↔ HCO3- (aq) + H2O(l) Ka2^-1 = 1.79 x 10^10
when we add it to equation 1
CaCO3(s) ↔ Ca2+(aq) + CO3-2(aq) Ksp = 4.5 x 10^-9
∴ the overall equation will be as we have mentioned before:
when H3O+ = H+
CaCO3(s) + H+(aq) ↔ Ca2+ (aq) + HCO3-(aq) K= 80.55
from the overall equation:
∴K = [Ca2+][HCO3-] / [H+]
when we have [Ca2+] = [HCO3-] so we can assume both = X
∴K = X^2 / [H+]
when we have the PH = 5.6 so we can get [H+]
PH = - ㏒[H+]
5.6 = -㏒[H]
∴[H] = 2.5 x 10^-6
so, by substitution on K expression:
∴ 80.55 = X^2 / (2.5 x10^-6)
∴X = 0.0142
∴[Ca2+] = X = 0.0142
Glass 1 Freshwater
The egg went directly to the base of the glass. Consequently it has sunk and did not drift
237.0
237 (1 glass)
1.000
Glass 2
Water with 2 teaspoons of salt
A similar outcome for glass 2 as container 1 when egg was set into the container it sank to the base.
248.4
237
1.048
Glass 3
Water with 3 teaspoons of salt
In reference to glass 1 and 2 the egg sank to the base for a third time.
254.1
237
1.072
Glass 4
Water with 4 teaspoons of salt
The egg remained gliding to where a little bit of the egg was standing out on the top, and when pushed down the egg returned up.
259.8
237
1.096
Hope this helps!