How can I separate gasoline and vegetable oil?

Look at sample problem 19.10 in the 8th ed Silberberg book. Write the Ksp expression. Find the concentrations of the ions you ne

777dan777 [17]

Answer:

Explanation:

From the information given:

$CaF_2 \to Ca^{2+} + 2F^-$

$Ksp = 3.2 \times 10^{-11}$

no of moles of $Ca^{2+}$ = 0.01 L × 0.0010 mol/L

no of moles of $Ca^{2+}$ = $1 \times 10^{-5} \ mol$

no of moles of $F^-$ = 0.01 L × 0.00010 mol/L

no of moles of $F^-$ = $1 \times 10^{-6}\ mol$

Total volume = 0.02 L

$[Ca^{2+}}] = \dfrac{1\times10^{-5} \ mol}{0.02 \ L} \\ \\ \\ \[[Ca^{2+}}] = 0.0005 \ mol/L$

$[F^{-}] = \dfrac{(1\times 10^{-6} \ mol)}{0.02 \ L}$

$[F^{-}] = 5 \times 10^{-5} \ mol/L$

$Q = [Ca^{2+}][F^-]^2 \\ \\ Q = 0.0005 \times (5\times 10^{-5})^2 \\ \\ Q = 1.25 \times 10^{-12}$

Since Q<ksp, then there will no be any precipitation of CaF2

3 0

3 years ago

Hard water often contains dissolved Ca2+ and Mg2+ ions. One way to soften water is to add phosphates. The phosphate ion forms in

avanturin [10]

5.5×10−2M in calcium chloride and 8.0×10−2M in magnesium nitrate.
What mass of sodium phosphate must be added to 1.5L of this solution to completely eliminate the hard water ion

1) Content of Ca (2+) ions

Calcium chloride = CaCl2

Ionization equation: CaCl2 ---> Ca (2+) + 2 Cl (-)

=> Molar ratios: 1 mol of CaCl2 : 1 mol Ca(2+) : 2 mol Cl(-)

Calculate the number of moles of CaCl2 in 1.5 liters of 5.5 * 10^-2 M solution

M = n / V => n = M*V = 5.5 * 10^ -2 M * 1.5 l = 0.0825 mol CaCl2

=> 0.0825 mol Ca(2+)

2) Number of phosphate ions needed to react with 0.0825 mol Ca(2+)

formula of phospahte ion: PO4 (3-)

molar ratio: 2PO4(3-) + 3Ca(2+) = Ca3 (PO4)2

Proportion: 2 mol PO4(3-) / 3 mol Ca(2+) = x / 0.0825 mol Ca(2+)

=> x = 0.0825 coml Ca(2+) * 2 mol PO4(3-) / 3 mol Ca(2+) = 0.055 mol PO4(3-)

3) Content of Mg(2+) ions

Ionization equation: Mg (NO3)2 ----> Mg(2+) + 2 NO3 (-)

Molar ratios: 1 mol Mg(NO3)2 : 1 mol Mg(2+) + 2 mol NO3(-)

number of moles of Mg(NO3)2 in 1.5 liter of 8.0 * 10^-2 M solution

n = M * V = 8.0 * 10^ -2 M * 1.5 liter = 0.12 moles Mg(NO3)2

ions of Mg(2+) = 0.12 mol Mg(NO3)2 * 1 mol Mg(2+) / mol Mg(NO3)2 = 0.12 mol Mg(2+)

4) Number of phosphate ions needed to react with 0.12 mol Mg(2+)

2PO4(3-) + 3Mg(2+) = Mg3(PO4)2

=> 2 mol PO4(3-) / 3 mol Mg(2+) = x / 0.12 mol Mg(2+)

=> x = 0.12 * 2/3 mol PO4(3-) = 0.16 mol PO4(3-)

5) Total number of moles of PO4(3-)

0.055 mol + 0.16 mol = 0.215 mol

6) Sodium phosphate

Sodium phosphate = Na3(PO4)

Na3PO4 ---> 3Na(+) + PO4(3-)

=> 1 mol Na3PO4 : 1 mol PO4(3-)

=> 0.215 mol PO4(3-) : 0.215 mol Na3PO4

mass in grams = number of moles * molar mass

molar mass of Na3 PO4 = 3*23 g/mol + 31 g/mol + 4*16 g/mol = 164 g/mol

=> mass in grams = 0.215 mol * 164 g/mol = 35.26 g

Answer: 35.26 g of sodium phosphate

5 0

3 years ago

HELP! A. W B. X C. Y D. Z

tamaranim1 [39]

Answer:

B

Explanation:

7 0

2 years ago

A student who stresses too much about his grades has incorrectly named an organic compound 3-propylhexane.

Brums [2.3K]

Answer:

None of these.

The correct answer should be, 4-ethylheptane.

Explanation:

In naming Alkanes, the general rules apply:

I. Identify the longest continuous carbon chain and name it as the root or parent name.

II. Identify any side chains and add their names and positions as a prefix to the parent chain.

III. When there are more than one type of side chain, name them alphabetically.

IV. Use hyphens between numbers and letters and commas between numbers.

V. Number your side chains to obtain the lowest number combinations possible.

For the above question,

first, attempt drawing only the carbon skeleton, of 3-propylhexane thus,

C-C-C-C-C-C

|

C-C-C

The longest continuous carbon chain (numbering from the top right) is 7 carbon atoms, hence, parent or root name is heptane. The 2 carbon atoms (at top left) not numbered make up the alkyl group called ethyl and since they are attached to carbon number 4 of the numbered carbon atoms ( whether the numbering is from top right to bottom right or vice versa ), their position and name should be written as a prefix to the parent name. That is why the organic compound is named, 4-ethylheptane.

Please note that in drawing the carbon skeleton of 3-propylhexane, the name is the same even if you start placing the bottom 3 carbon atoms on the 3rd carbon (top) from the left or from the right because the numbering can start from any side to achieve the lowest number combinations of numbering common Alkanes.

7 0

3 years ago

Reaction of 0.028 g of magnesium with excess hydrochloric acid generated 31.0 mL of hydrogen gas. The gas was collected by water

MA_775_DIABLO [31]

Explanation:

(a) It is given that magnesium is reacted with hydrochloric acid and the hydrogen evolved is collected at top. This means that hydrochloric acid will be present in a solution (HCl + Water) and the solvent will be water.

Due to evaporation some amount of water will have evaporated and would be present in vapor phase. Therefore, when the reaction occurs only hydrogen will not be present in vapor phase but, will be accompanied by water vapors as well .

Hence, Dalton's law the total pressure of the system will be sum of pressure exerted by hydrogen gas and pressure exerted by water vapors .

Let us assume that the partial pressure of hydrogen gas be " $P_H_{2}$ "

And, the partial pressure of water will be nothing but the vapor pressure of water,

Vapor pressure of water = $P_{water}$

= 19.8 mm Hg

Total pressure of the system = 746 mm Hg

Total pressure = $P_H_{2} + P_{water}$

746 = $P_H_{2}$ + 19.8

or, $P_H_{2}$ = 746-19.8

= 726.2 mm Hg

Hence, partial pressure of hydrogen gas is 726.2 mm Hg.

(b) To calculate volume at STP, we will first calculate at $22^{o}C$ and 726.2 mm Hg and than convert it to STP conditions.

Therefore, to calculate volume at $22^{o}C$ and 726.2 mm Hg we will make use of ideal gas law as follows.

P = 726.2 mm Hg

= $\frac{726.2}{760}$

= 0.955 atm

T = $22^{o}C$

= 22+273.15 = 295.15 K

V = 31 ml = $31 \times 10^{-3}$ Litre

According to the ideal gas law ,

PV = nRT

where, P = pressure of the system ,

V = volume of the gas

N = number of moles

R = 0.0821 liter atm/mole K

T = Temperature

Hence, putting the given values into the above formula as follows.

$0.955 \times 31 \times 10^{-3} = N \times 0.0821 \times 295.15$

N = $1.222 \times 10^{-3}$ moles

Now, the moles of hydrogen won't change. Therefore, let us calculate volume at STP of $1.222 \times 10^{-3}$ moles of hydrogen.

Now, at STP T = 273.15 K , P = 1 atm and N = $1.222 \times 10^{-3}$ moles

$1 \times V = 1.222 \times 10^{-3} \times 0.0821 \times 273.15 K$

V = 0.027398 Litre

= $0.027398 \times 1000$ (as 1 L = 1000 ml)

= 27.398 ml

Therefore, volume of hydrogen at STP is 27.398 ml .

(c) Now, we can write the the reaction for this case as follows.

$Mg + 2HCl \rightarrow MgCl_{2} + H_{2}$

As, weight of magnesium = 0.028 grams

Molar mass of magnesium = 24.3 grams/mole

Number of moles of magnesium = $\frac{mass}{\text{molar mass}}$

= $\frac{0.028}{24.3}$

= $1.15226 \times 10^{-3}$ moles

Since, it can be seen from the reaction that

1 mole of Magnesium = 1 mole of hydrogen

and, moles of hydrogen = $1.15226 \times 10^{-3}$ moles

= 0.001523 moles

Hence, theoretical number of moles of hydrogen that can be produced from 0.028 grams of Mg is 0.001523 moles

8 0

3 years ago